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Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II)
https://oist.repo.nii.ac.jp/records/1630
https://oist.repo.nii.ac.jp/records/16302ac1fbed-fae5-4c14-92c1-b1e1d89a4634
名前 / ファイル | ライセンス | アクション |
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Just Accepted online version-1 (286.7 kB)
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SI Khaskin ACScatalysis _ modified after review 3-2 (9.5 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-07-17 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II) | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Vojkovsky, Tomas
× Vojkovsky, Tomas× Deolka, Shubham× Stepanova, Saiyyna× Roy, Michael C.× Khaskin, Eugene |
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書誌情報 |
en : ACS Catalysis 巻 10, 号 12, p. 6810-6815, 発行日 2020-04-20 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Sulfones and sulfonamides with an α-CH bond can be easily alkylated by aliphatic alcohols to add the carbon skeleton of the alcohol via a one-step, Ru(II)-catalyzed redox neutral reaction. The reaction requires a substoichiometric amount of base and produces only water as a byproduct. Several pharmaceutically relevant functional groups such as piperidine, morpholine, etc. are well-tolerated under the reaction conditions to give higher value-added products in one step from widely available substrates. The reaction proceeds through a sulfone carbanion addition to an in-situ-generated aldehyde formed via catalytic dehydrogenation and subsequent catalyst-mediated replacement of the secondary alcohol by hydrogen. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2155-5435 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/acscatal.0c00206 | |||||
権利 | ||||||
権利情報 | © 2020 American Chemical Society | |||||
権利 | ||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/full/10.1021/acscatal.0c00206. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/full/10.1021/acscatal.0c00206 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |