The presence of Pd···Cu and Pd···Pd interactions as well as order of metal atoms in a chain held by a modular polynucleating ligand is controlled by coordinating ability of anions, leading to selective formation of bi- and tetranuclear Pd/Cu and Pd4 chains. Metal-metal cooperative reactivity in these complexes was tested in Ar–O bond formation and alkyne activation.
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Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal-metal interactions
D1CC04212B
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