WEKO3
アイテム
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Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High‐Valent Nickel Complexes
https://oist.repo.nii.ac.jp/records/2328
https://oist.repo.nii.ac.jp/records/2328331b0f87-277c-4ed0-9cc6-9467d4ee1df4
名前 / ファイル | ライセンス | アクション |
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anie.202109953a (2.0 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-10-15 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High‐Valent Nickel Complexes | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | C-H bond functionalization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | nickel | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | photoreactivity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | radical formation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | trifluoromethylation | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Deolka, Shubham
× Deolka, Shubham× Govindarajan, Ramadoss× Khaskin, Eugene× Fayzullin, Robert R.× Roy, Michael C.× Khusnutdinova, Julia R. |
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書誌情報 |
en : Angewandte Chemie International Edition 発行日 2021-10-07 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | We describe a series of air-stable NiIII complexes supported by a simple, robust naphthyridine-based ligand. Access to the high-valent oxidation state is enabled by the CF3 ligands on the nickel, while the naphthyridine exhibits either a monodentate or bidentate coordination mode that depends on the oxidation state and sterics, and enables facile aerobic oxidation of NiII to NiIII. These NiIII complexes act as efficient catalysts for photoinduced C(sp2)−H bond trifluoromethylation reactions of (hetero)arenes using versatile synthetic protocols. This blue LED light-mediated catalytic protocol proceeds via a radical pathway and demonstrates potential in the late-stage functionalization of drug analogs. | |||||
出版者 | ||||||
出版者 | John Wiley & Sons, Inc. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1433-7851 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1521-3773 | |||||
PubMed番号 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/34477296 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/anie.202109953 | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: Deolka, S., Govindarajan, R., Khaskin, E., Fayzullin, R.R., Roy, M.C. and Khusnutdinova, J.R. Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High-Valent Nickel Complexes, Angewandte Chemie International Edition, 2021, which has been published in final form at https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202109953. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://onlinelibrary.wiley.com/doi/10.1002/anie.202109953 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |