WEKO3
アイテム
{"_buckets": {"deposit": "fe73927d-72e7-4a53-a619-c210cac14b32"}, "_deposit": {"created_by": 31, "id": "2841", "owners": [31], "pid": {"revision_id": 0, "type": "depid", "value": "2841"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00002841", "sets": ["35"]}, "author_link": ["18160", "18158", "18159"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-10-28", "bibliographicIssueDateType": "Issued"}, "bibliographic_titles": [{}, {"bibliographic_title": "Chemical Science", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Govindarajan, R."}], "nameIdentifiers": [{"nameIdentifier": "18158", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Deolka, Shubham"}], "nameIdentifiers": [{"nameIdentifier": "18159", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Khusnutdinova, Julia R."}], "nameIdentifiers": [{"nameIdentifier": "18160", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "Heterobi- and multimetallic complexes providing close proximity between several metal centers serve as active species in artificial and enzymatic catalysis, and in model systems, showing unique modes of metal–metal cooperative bond activation. Through the rational design of well-defined, unsymmetrical ligand scaffolds, we create a convenient approach to support the assembly of heterometallic species in a well-defined and site-specific manner, preventing them from scrambling and dissociation. In this perspective, we will outline general strategies for the design of unsymmetrical ligands to support heterobi- and multimetallic complexes that show reactivity in various types of heterometallic cooperative bond activation.", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1039/D2SC04263K", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://pubs.rsc.org/en/content/articlelanding/2022/SC/D2SC04263K", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2022 The Author(s)"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2041-6520", "subitem_source_identifier_type": "ISSN"}, {"subitem_source_identifier": "2041-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-11-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Govindarajan-2022-Heterometallic bond activati_VoR.pdf", "filesize": [{"value": "4.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_9", "mimetype": "application/pdf", "size": 4700000.0, "url": {"label": "Govindarajan-2022-Heterometallic bond activati_VoR", "url": "https://oist.repo.nii.ac.jp/record/2841/files/Govindarajan-2022-Heterometallic bond activati_VoR.pdf"}, "version_id": "147bc49a-506f-47b6-8e5a-9f5be354d58c"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "31", "path": ["35"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/2841", "pubdate": {"attribute_name": "公開日", "attribute_value": "2022-11-14"}, "publish_date": "2022-11-14", "publish_status": "0", "recid": "2841", "relation": {}, "relation_version_is_last": true, "title": ["Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites"], "weko_shared_id": 31}
Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites
https://oist.repo.nii.ac.jp/records/2841
https://oist.repo.nii.ac.jp/records/2841c73ae770-4d14-4513-a244-fc2a4d73ef33
名前 / ファイル | ライセンス | アクション |
---|---|---|
Govindarajan-2022-Heterometallic bond activati_VoR (4.7 MB)
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2022-11-14 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Govindarajan, R.
× Govindarajan, R.× Deolka, Shubham× Khusnutdinova, Julia R. |
|||||
書誌情報 |
en : Chemical Science 発行日 2022-10-28 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Heterobi- and multimetallic complexes providing close proximity between several metal centers serve as active species in artificial and enzymatic catalysis, and in model systems, showing unique modes of metal–metal cooperative bond activation. Through the rational design of well-defined, unsymmetrical ligand scaffolds, we create a convenient approach to support the assembly of heterometallic species in a well-defined and site-specific manner, preventing them from scrambling and dissociation. In this perspective, we will outline general strategies for the design of unsymmetrical ligands to support heterobi- and multimetallic complexes that show reactivity in various types of heterometallic cooperative bond activation. | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2041-6520 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2041-6539 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1039/D2SC04263K | |||||
権利 | ||||||
権利情報 | © 2022 The Author(s) | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2022/SC/D2SC04263K | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |