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Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide
https://oist.repo.nii.ac.jp/records/819
https://oist.repo.nii.ac.jp/records/8197a8275a1-5e72-491b-b35c-914958f1698a
名前 / ファイル | ライセンス | アクション |
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repository_ACSCatal (589.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-03-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Dubey, Abhishek
× Dubey, Abhishek× Nencini, Luca× Fayzullin, Robert R.× Nervi, Carlo× Khusnutdinova, Julia R. |
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書誌情報 |
en : ACS Catalysis 巻 7, 号 6, p. 3864-3868, 発行日 2017-04-28 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Developing new, efficient catalysts that contain Earth-abundant metals and simple, robust ligands for CO2 hydrogenation is important to create cost-effective processes of CO2 utilization. Inspired by nature, which utilizes an ortho-OH-substituted pyridine motif in Fe-containing hydrogenases, we developed a Mn complex with a simple N-donor ligand, 6,6′-dihydroxy-2,2′-bipyridine, that acts as an efficient catalyst for CO2 hydrogenation. Turnover numbers of 6250 for hydrogenation of CO2 to formate in the presence of DBU were achieved. Moreover, hydrogenation of CO2 to formamide was achieved in the presence of a secondary amine. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2155-5435 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/acscatal.7b00943 | |||||
権利 | ||||||
権利情報 | © 2017 American Chemical Society | |||||
権利 | ||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work, see https://pubs.acs.org/doi/10.1021/acscatal.7b00943 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/acscatal.7b00943 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |