WEKO3
アイテム
{"_buckets": {"deposit": "f3ebc029-5572-41be-90de-9a638405422c"}, "_deposit": {"created_by": 30, "id": "1463", "owners": [30], "pid": {"revision_id": 0, "type": "depid", "value": "1463"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00001463", "sets": ["177"]}, "author_link": ["8872", "8877", "8868", "8862", "8867", "8870", "8878", "8873", "8875", "8863", "8874", "8866", "8876", "8879", "8880", "8865", "8864", "8871", "8869"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-03-20", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageStart": "1490", "bibliographicVolumeNumber": "11", "bibliographic_titles": [{}, {"bibliographic_title": "Nature Communications", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Riss, Alexander"}], "nameIdentifiers": [{"nameIdentifier": "8862", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Richter, Marcus"}], "nameIdentifiers": [{"nameIdentifier": "8863", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Paz, Alejandro Pérez"}], "nameIdentifiers": [{"nameIdentifier": "8864", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wang, Xiao-Ye"}], "nameIdentifiers": [{"nameIdentifier": "8865", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Raju, Rajesh"}], "nameIdentifiers": [{"nameIdentifier": "8866", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "He, Yuanqin"}], "nameIdentifiers": [{"nameIdentifier": "8867", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ducke, Jacob"}], "nameIdentifiers": [{"nameIdentifier": "8868", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Corral, Eduardo"}], "nameIdentifiers": [{"nameIdentifier": "8869", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wuttke, Michael"}], "nameIdentifiers": [{"nameIdentifier": "8870", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Seufert, Knud"}], "nameIdentifiers": [{"nameIdentifier": "8871", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Garnica, Manuela"}], "nameIdentifiers": [{"nameIdentifier": "8872", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Rubio, Angel"}], "nameIdentifiers": [{"nameIdentifier": "8873", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "V. Barth, Johannes"}], "nameIdentifiers": [{"nameIdentifier": "8874", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Narita, Akimitsu"}], "nameIdentifiers": [{"nameIdentifier": "8875", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Müllen, Klaus"}], "nameIdentifiers": [{"nameIdentifier": "8876", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Berger, Reinhard"}], "nameIdentifiers": [{"nameIdentifier": "8877", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Feng, Xinliang"}], "nameIdentifiers": [{"nameIdentifier": "8878", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Palma, Carlos-Andres"}], "nameIdentifiers": [{"nameIdentifier": "8879", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Auwärter, Willi"}], "nameIdentifiers": [{"nameIdentifier": "8880", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "The vast potential of organic materials for electronic, optoelectronic and spintronic devices entails substantial interest in the fabrication of pi-conjugated systems with tailored functionality directly at insulating interfaces. On-surface fabrication of such materials on non-metal surfaces remains to be demonstrated with high yield and selectivity. Here we present the synthesis of polyaromatic chains on metallic substrates, insulating layers, and in the solid state. Scanning probe microscopy shows the formation of azaullazine repeating units on Au(111), Ag(111), and h-BN/Cu(111), stemming from intermolecular homo-coupling via cycloaddition reactions of CN-substituted polycyclic aromatic azomethine ylide (PAMY) intermediates followed by subsequent dehydrogenation. Matrix-assisted laser desorption/ionization (MALDI) mass spectrometry demonstrates that the reaction also takes place in the solid state in the absence of any catalyst. Such intermolecular cycloaddition reactions are promising methods for direct synthesis of regioregular polyaromatic polymers on arbitrary insulating surfaces.", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": "Nature Research "}]}, "item_10001_relation_13": {"attribute_name": "PubMedNo.", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:pmid/32198456 ", "subitem_relation_type_select": "PMID"}}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1038/s41467-020-15210-2", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_16": {"attribute_name": "情報源", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://creativecommons.org/licenses/by/4.0/"}]}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.nature.com/articles/s41467-020-15210-2", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2020 The Author(s)"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2041-1723", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-05-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Riss-2020-Polycyclic aromatic chains on metals.pdf", "filesize": [{"value": "3.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Creative Commons Attribution 4.0 International(https://creativecommons.org/licenses/by/4.0/)", "licensetype": "license_free", "mimetype": "application/pdf", "size": 3600000.0, "url": {"label": "Riss-2020-Polycyclic aromatic chains on metals", "url": "https://oist.repo.nii.ac.jp/record/1463/files/Riss-2020-Polycyclic aromatic chains on metals.pdf"}, "version_id": "91afe3b5-36dc-4c4c-83d0-7abb7a8ba14e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditions", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditions", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "30", "path": ["177"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/1463", "pubdate": {"attribute_name": "公開日", "attribute_value": "2020-05-07"}, "publish_date": "2020-05-07", "publish_status": "0", "recid": "1463", "relation": {}, "relation_version_is_last": true, "title": ["Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditions"], "weko_shared_id": 30}
Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditions
https://oist.repo.nii.ac.jp/records/1463
https://oist.repo.nii.ac.jp/records/146326166bb6-6b44-4a0c-a2c1-0f4e919a5a8d
名前 / ファイル | ライセンス | アクション |
---|---|---|
Riss-2020-Polycyclic aromatic chains on metals (3.6 MB)
|
Creative Commons Attribution 4.0 International(https://creativecommons.org/licenses/by/4.0/)
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2020-05-07 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditions | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Riss, Alexander
× Riss, Alexander× Richter, Marcus× Paz, Alejandro Pérez× Wang, Xiao-Ye× Raju, Rajesh× He, Yuanqin× Ducke, Jacob× Corral, Eduardo× Wuttke, Michael× Seufert, Knud× Garnica, Manuela× Rubio, Angel× V. Barth, Johannes× Narita, Akimitsu× Müllen, Klaus× Berger, Reinhard× Feng, Xinliang× Palma, Carlos-Andres× Auwärter, Willi |
|||||
書誌情報 |
en : Nature Communications 巻 11, 号 1, p. 1490, 発行日 2020-03-20 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The vast potential of organic materials for electronic, optoelectronic and spintronic devices entails substantial interest in the fabrication of pi-conjugated systems with tailored functionality directly at insulating interfaces. On-surface fabrication of such materials on non-metal surfaces remains to be demonstrated with high yield and selectivity. Here we present the synthesis of polyaromatic chains on metallic substrates, insulating layers, and in the solid state. Scanning probe microscopy shows the formation of azaullazine repeating units on Au(111), Ag(111), and h-BN/Cu(111), stemming from intermolecular homo-coupling via cycloaddition reactions of CN-substituted polycyclic aromatic azomethine ylide (PAMY) intermediates followed by subsequent dehydrogenation. Matrix-assisted laser desorption/ionization (MALDI) mass spectrometry demonstrates that the reaction also takes place in the solid state in the absence of any catalyst. Such intermolecular cycloaddition reactions are promising methods for direct synthesis of regioregular polyaromatic polymers on arbitrary insulating surfaces. | |||||
出版者 | ||||||
出版者 | Nature Research | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2041-1723 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/32198456 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1038/s41467-020-15210-2 | |||||
権利 | ||||||
権利情報 | © 2020 The Author(s) | |||||
情報源 | ||||||
関連名称 | https://creativecommons.org/licenses/by/4.0/ | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.nature.com/articles/s41467-020-15210-2 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |