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Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes
https://oist.repo.nii.ac.jp/records/1593
https://oist.repo.nii.ac.jp/records/1593eb8675b8-c392-4347-b318-aaf8dc6982a3
名前 / ファイル | ライセンス | アクション |
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Manuscript (1.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-07-02 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Dubey, Abhishek
× Dubey, Abhishek× Rahaman, S. M. Wahidur× Fayzullin, Robert R.× Khusnutdinova, Julia R. |
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書誌情報 |
en : ChemCatChem 巻 11, 号 16, p. 3844-3852, 発行日 2019-04-02 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Utilization of hydroxy‐substituted bipyridine ligands in transition metal catalysis mimicking [Fe]‐hydrogenase has been shown to be a promising approach in developing new catalysts for hydrogenation. For example, MnI complexes with 6,6′‐dihydroxy‐2,2′‐bipyridine ligand have been previously shown to be active catalysts for CO2 hydrogenation. In this work, simple bipyridine‐based Mn catalysts were developed that act as active catalysts for transfer hydrogenation of ketones, aldehydes and imines. For the first time, Mn‐catalyzed transfer hydrogenation of N ‐heterocycles was reported. The highest catalytic activity among complexes with variously substituted ligands was observed for the complex bearing two OH groups in bipyridine. Deuterium labeling experiments suggest a monohydride pathway. | |||||
出版者 | ||||||
出版者 | John Wiley & Sons | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1867-3880 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1867-3899 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/cctc.201900358 | |||||
権利 | ||||||
権利情報 | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: A. Dubey, S. M. W. Rahaman, R. R. Fayzullin, J. R. Khusnutdinova. Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes. ChemCatChem 2019, 11, 3844., which has been published in final form at https://doi.org/10.1002/cctc.201900358. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
関連サイト | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/cctc.201900358 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |