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On-Surface Synthesis of Unsaturated Carbon Nanostructures with Regularly Fused Pentagon–Heptagon Pairs
https://oist.repo.nii.ac.jp/records/1677
https://oist.repo.nii.ac.jp/records/1677cd0d0d59-1a4b-4c8b-bb4a-4813e9b0c579
名前 / ファイル | ライセンス | アクション |
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Hou-2020-On-Surface Synthesis of Unsaturated C (5.6 MB)
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Creative Commons Attribution 4.0 International (https://creativecommons.org/licenses/by/4.0/)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-08-14 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | On-Surface Synthesis of Unsaturated Carbon Nanostructures with Regularly Fused Pentagon–Heptagon Pairs | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Hou, Ian Cheng-Yi
× Hou, Ian Cheng-Yi× Sun, Qiang× Eimre, Kristjan× Di Giovannantonio, Marco× Urgel, José I.× Ruffieux, Pascal× Narita, Akimitsu× Fasel, Roman× Müllen, Klaus |
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書誌情報 |
en : Journal of the American Chemical Society 巻 142, 号 23, p. 10291-10296, 発行日 2020-05-19 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Multiple fused pentagon–heptagon pairs are frequently found as defects at the grain boundaries of the hexagonal graphene lattice and are suggested to have a fundamental influence on graphene-related materials. However, the construction of sp2-carbon skeletons with multiple regularly fused pentagon–heptagon pairs is challenging. In this work, we found that the pentagon–heptagon skeleton of azulene was rearranged during the thermal reaction of an azulene-incorporated organometallic polymer on Au(111). The resulting sp2-carbon frameworks were characterized by high-resolution scanning probe microscopy techniques and feature novel polycyclic architectures composed of multiple regularly fused pentagon–heptagon pairs. Moreover, the calculated analysis of its aromaticity revealed a peculiar polar electronic structure. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0002-7863 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1520-5126 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/32428409 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/jacs.0c03635 | |||||
権利 | ||||||
権利情報 | © 2020 American Chemical Society | |||||
権利 | ||||||
権利情報 | ACS AuthorChoice with CC-BY | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/jacs.0c03635 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |