WEKO3
アイテム
{"_buckets": {"deposit": "80597958-6d7e-4b3a-87f2-e503354c2439"}, "_deposit": {"created_by": 28, "id": "1678", "owners": [28], "pid": {"revision_id": 0, "type": "depid", "value": "1678"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00001678", "sets": ["177"]}, "author_link": ["10075", "10076", "10082", "10079", "10081", "10074", "10078", "10080", "10077"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-06-26", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "28", "bibliographicPageEnd": "12050", "bibliographicPageStart": "12046", "bibliographicVolumeNumber": "142", "bibliographic_titles": [{}, {"bibliographic_title": "Journal of the American Chemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Di Giovannantonio, Marco"}], "nameIdentifiers": [{"nameIdentifier": "10074", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yao, Xuelin"}], "nameIdentifiers": [{"nameIdentifier": "10075", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Eimre, Kristjan"}], "nameIdentifiers": [{"nameIdentifier": "10076", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Urgel, José I."}], "nameIdentifiers": [{"nameIdentifier": "10077", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ruffieux, Pascal"}], "nameIdentifiers": [{"nameIdentifier": "10078", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Pignedoli, Carlo A."}], "nameIdentifiers": [{"nameIdentifier": "10079", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Müllen, Klaus"}], "nameIdentifiers": [{"nameIdentifier": "10080", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fasel, Roman"}], "nameIdentifiers": [{"nameIdentifier": "10081", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Narita, Akimitsu"}], "nameIdentifiers": [{"nameIdentifier": "10082", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "Coronoids, polycyclic aromatic hydrocarbons with geometrically defined cavities, are promising model structures of porous graphene. Here, we report the on-surface synthesis of C168 and C140 coronoids, referred to as [6]- and [5]coronoid, respectively, using 5,9-dibromo-14-phenylbenzo[m]tetraphene as the precursor. These coronoids entail large cavities (\u003e1 nm) with inner zigzag edges, distinct from their outer armchair edges. While [6]coronoid is planar, [5]coronoid is not. Low-temperature scanning tunneling microscopy/spectroscopy and noncontact atomic force microscopy unveil structural and electronic properties in accordance with those obtained from density functional theory calculations. Detailed analysis of ring current effects identifies the rings with the highest aromaticity of these coronoids, whose pattern matches their Clar structure. The pores of the obtained coronoids offer intriguing possibilities of further functionalization toward advanced host–guest applications.", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": "American Chemical Society"}]}, "item_10001_relation_13": {"attribute_name": "PubMedNo.", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:pmid/32589416", "subitem_relation_type_select": "PMID"}}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1021/jacs.0c05268", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://pubs.acs.org/doi/10.1021/jacs.0c05268", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2020 American Chemical Society"}, {"subitem_rights": "ACS AuthorChoice with CC-BY"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "ISSN"}, {"subitem_source_identifier": "1520-5126", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-08-17"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Di Giovannanton-2020-Large-Cavity Coronoids wi.pdf", "filesize": [{"value": "3.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Creative Commons Attribution 4.0 International (https://creativecommons.org/licenses/by/4.0/)", "licensetype": "license_free", "mimetype": "application/pdf", "size": 3900000.0, "url": {"label": "Di Giovannanton-2020-Large-Cavity Coronoids wi", "url": "https://oist.repo.nii.ac.jp/record/1678/files/Di Giovannanton-2020-Large-Cavity Coronoids wi.pdf"}, "version_id": "b5ccb092-599b-4bb5-bbf9-e038691631a8"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Large-Cavity Coronoids with Different Inner and Outer Edge Structures", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Large-Cavity Coronoids with Different Inner and Outer Edge Structures", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "28", "path": ["177"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/1678", "pubdate": {"attribute_name": "公開日", "attribute_value": "2020-08-17"}, "publish_date": "2020-08-17", "publish_status": "0", "recid": "1678", "relation": {}, "relation_version_is_last": true, "title": ["Large-Cavity Coronoids with Different Inner and Outer Edge Structures"], "weko_shared_id": 28}
Large-Cavity Coronoids with Different Inner and Outer Edge Structures
https://oist.repo.nii.ac.jp/records/1678
https://oist.repo.nii.ac.jp/records/16780ef21e21-0922-40ea-bf0a-a20135470f52
名前 / ファイル | ライセンス | アクション |
---|---|---|
Di Giovannanton-2020-Large-Cavity Coronoids wi (3.9 MB)
|
Creative Commons Attribution 4.0 International (https://creativecommons.org/licenses/by/4.0/)
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2020-08-17 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Large-Cavity Coronoids with Different Inner and Outer Edge Structures | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Di Giovannantonio, Marco
× Di Giovannantonio, Marco× Yao, Xuelin× Eimre, Kristjan× Urgel, José I.× Ruffieux, Pascal× Pignedoli, Carlo A.× Müllen, Klaus× Fasel, Roman× Narita, Akimitsu |
|||||
書誌情報 |
en : Journal of the American Chemical Society 巻 142, 号 28, p. 12046-12050, 発行日 2020-06-26 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Coronoids, polycyclic aromatic hydrocarbons with geometrically defined cavities, are promising model structures of porous graphene. Here, we report the on-surface synthesis of C168 and C140 coronoids, referred to as [6]- and [5]coronoid, respectively, using 5,9-dibromo-14-phenylbenzo[m]tetraphene as the precursor. These coronoids entail large cavities (>1 nm) with inner zigzag edges, distinct from their outer armchair edges. While [6]coronoid is planar, [5]coronoid is not. Low-temperature scanning tunneling microscopy/spectroscopy and noncontact atomic force microscopy unveil structural and electronic properties in accordance with those obtained from density functional theory calculations. Detailed analysis of ring current effects identifies the rings with the highest aromaticity of these coronoids, whose pattern matches their Clar structure. The pores of the obtained coronoids offer intriguing possibilities of further functionalization toward advanced host–guest applications. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0002-7863 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1520-5126 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/32589416 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/jacs.0c05268 | |||||
権利 | ||||||
権利情報 | © 2020 American Chemical Society | |||||
権利 | ||||||
権利情報 | ACS AuthorChoice with CC-BY | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/jacs.0c05268 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |