WEKO3
アイテム
{"_buckets": {"deposit": "35338392-7172-4728-b6c9-76127ba92104"}, "_deposit": {"created_by": 31, "id": "2722", "owners": [31], "pid": {"revision_id": 0, "type": "depid", "value": "2722"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00002722", "sets": ["35"]}, "author_link": ["17550", "17544", "17545", "17547", "17549", "17546", "17548"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-06-30", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "44", "bibliographicPageStart": "e202201639", "bibliographicVolumeNumber": "28", "bibliographic_titles": [{}, {"bibliographic_title": "Chemistry – A European Journal", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Govindarajan, Ramadoss"}], "nameIdentifiers": [{"nameIdentifier": "17544", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Deolka, Shubham"}], "nameIdentifiers": [{"nameIdentifier": "17545", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Khaskin, Eugene"}], "nameIdentifiers": [{"nameIdentifier": "17546", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fayzullin, Robert R."}], "nameIdentifiers": [{"nameIdentifier": "17547", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Pal, Shrinwantu"}], "nameIdentifiers": [{"nameIdentifier": "17548", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Vasylevskyi, Serhii"}], "nameIdentifiers": [{"nameIdentifier": "17549", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Khusnutdinova, Julia R."}], "nameIdentifiers": [{"nameIdentifier": "17550", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "We report a series of heterobimetallic Pt/Zn and Pt/Ca complexes to study the effect of proximity of a dicationic base metal on the organometallic Pt species. Varying degrees of Pt⋅⋅⋅Zn and Zn interaction with the bridging Me group are achieved, showcasing snapshots of a hypothetical process of retrotransmetalation from Pt to Zn. In contrast, only weak interactions were observed for Ca with a Pt-bound Me group. Activation of H2, B−H and Si−H bonds leads to the formation of hydride-bridged Pt−H−Zn complexes, which is not observed in the absence of Zn, pointing out the importance of metal-metal cooperation. Reactivity of PtMe2/M2+ with terminal acetylene, water and methanol is also studied, leading to facile protonation of one of the Me groups at the Pt center only when Zn is present. This study sheds light on various ways in which the presence of a 2+ metal cation significantly affects the reactivity of a common organoplatinum complex.", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": " John Wiley \u0026 Sons, Inc."}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1002/chem.202201639", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201639", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2022 Wiley-VCH GmbH"}, {"subitem_rights": "This is the peer reviewed version of the following article: R. Govindarajan, S. Deolka, E. Khaskin, R. R. Fayzullin, S. Pal, S. Vasylevskyi, J. R. Khusnutdinova, Chem. Eur. J. 2022, 28, e202201639, which has been published in final form at https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201639. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}, {"subitem_source_identifier": "1521-3765", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-06-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Chemistry A European J - 2022 - Govindarajan -am.pdf", "filesize": [{"value": "1.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1400000.0, "url": {"label": "Chemistry A European J - 2022 - Govindarajan -am", "url": "https://oist.repo.nii.ac.jp/record/2722/files/Chemistry A European J - 2022 - Govindarajan -am.pdf"}, "version_id": "1202d1c4-d0e9-4e6d-b7ee-a936d636b909"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "heterobimetallic complexes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "platinum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metal-metal cooperation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metal-metal interactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "zinc", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "H-2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "H-2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "31", "path": ["35"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/2722", "pubdate": {"attribute_name": "公開日", "attribute_value": "2022-07-28"}, "publish_date": "2022-07-28", "publish_status": "0", "recid": "2722", "relation": {}, "relation_version_is_last": true, "title": ["H-2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation"], "weko_shared_id": 31}
H-2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation
https://oist.repo.nii.ac.jp/records/2722
https://oist.repo.nii.ac.jp/records/2722dbcfe4d0-b049-42b3-aaf6-e33209d673cc
名前 / ファイル | ライセンス | アクション |
---|---|---|
Chemistry A European J - 2022 - Govindarajan -am (1.4 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2022-07-28 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | H-2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | heterobimetallic complexes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | platinum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | metal-metal cooperation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | metal-metal interactions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | zinc | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Govindarajan, Ramadoss
× Govindarajan, Ramadoss× Deolka, Shubham× Khaskin, Eugene× Fayzullin, Robert R.× Pal, Shrinwantu× Vasylevskyi, Serhii× Khusnutdinova, Julia R. |
|||||
書誌情報 |
en : Chemistry – A European Journal 巻 28, 号 44, p. e202201639, 発行日 2022-06-30 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | We report a series of heterobimetallic Pt/Zn and Pt/Ca complexes to study the effect of proximity of a dicationic base metal on the organometallic Pt species. Varying degrees of Pt⋅⋅⋅Zn and Zn interaction with the bridging Me group are achieved, showcasing snapshots of a hypothetical process of retrotransmetalation from Pt to Zn. In contrast, only weak interactions were observed for Ca with a Pt-bound Me group. Activation of H2, B−H and Si−H bonds leads to the formation of hydride-bridged Pt−H−Zn complexes, which is not observed in the absence of Zn, pointing out the importance of metal-metal cooperation. Reactivity of PtMe2/M2+ with terminal acetylene, water and methanol is also studied, leading to facile protonation of one of the Me groups at the Pt center only when Zn is present. This study sheds light on various ways in which the presence of a 2+ metal cation significantly affects the reactivity of a common organoplatinum complex. | |||||
出版者 | ||||||
出版者 | John Wiley & Sons, Inc. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0947-6539 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1521-3765 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/chem.202201639 | |||||
権利 | ||||||
権利情報 | © 2022 Wiley-VCH GmbH | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: R. Govindarajan, S. Deolka, E. Khaskin, R. R. Fayzullin, S. Pal, S. Vasylevskyi, J. R. Khusnutdinova, Chem. Eur. J. 2022, 28, e202201639, which has been published in final form at https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201639. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201639 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |