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In-situ shear-banding quantification of surfactant solutions in straight microfluidic channels
https://oist.repo.nii.ac.jp/records/305
https://oist.repo.nii.ac.jp/records/3058eddd93a-5f69-403a-b217-a40c5b0d6388
名前 / ファイル | ライセンス | アクション |
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1.4985379 (4.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-06-16 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | In-situ shear-banding quantification of surfactant solutions in straight microfluidic channels | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Lutz-Bueno, Viviane
× Lutz-Bueno, Viviane× Pasquino, Rossana× Haward, Simon J.× Shen, Amy Q.× Fischer, Peter |
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書誌情報 |
en : Journal of Rheology 巻 61, 号 4, p. 769, 発行日 2017-06-15 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Surfactant molecules aggregate into various micellar morphologies, depending on temperature, concentration, formulation, and flow. Micellar solutions are known to undergo shear-banding when subjected to strong shear rates, as the fluid spontaneously divides itself into bands of high and low-shear rate, both under the same applied shear stress. This phenomenon occurs because of the complex structure of micellar solutions, which undergo phase transitions upon applied flow, changing the viscosity accordingly. Here, we study shear-banding of micellar solutions in one of the simplest microfluidic geometries, a straight planar channel with rectangular cross section. Four solutions with similar zero-shear viscosity and nonlinear rheological response, but different structures are compared to investigate the flow-structure relation and its impact on shear-banding. Micellar solutions are prepared by adding different amounts of the same organic salt, sodium salicylate, to surfactant molecules with different headgroups, i.e., cetyltrimethylammonium bromide and cetylpyridinium chloride. From spatially resolved microparticle image velocimetry and flow-induced birefringence measurements, the shear rate and shear stress profiles developed on the xy-plane of a planar microchannel are obtained from a series of volumetric flow rates. Based on these profiles, in-situ rheological parameters, such as the local viscosity, are calculated by applying the stress-optical rule. The local response in a microfluidic channel is compared to the bulk rheological response in a rotational rheometer and clear correlations are found especially for the stress plateau region, the fingerprint of shear-banding. Based on the local rheological characterization of these micellar solutions, the development and growth of shear-bands is observed and quantified. The role of salt concentration and surfactant headgroup on the resulting micellar morphology is discussed, as well as its impact on the development of shear-banding. | |||||
出版者 | ||||||
出版者 | The Society of Rheology | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0148-6055 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1520-8516 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1122/1.4985379 | |||||
権利 | ||||||
権利情報 | © 2017 The Society of Rheology | |||||
権利 | ||||||
権利情報 | This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in Lutz-Bueno, V., Pasquino, R., Haward, S. J., Shen, A. Q., & Fischer, P. (2017). In-situ shear-banding quantification of surfactant solutions in straight microfluidic channels. Journal of Rheology, 61(4), 769-783. doi:10.1122/1.4985379 and may be found at https://doi.org/10.1122/1.4985379 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://sor.scitation.org/doi/abs/10.1122/1.4985379 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |