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Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels
https://oist.repo.nii.ac.jp/records/982
https://oist.repo.nii.ac.jp/records/9825726fc85-636a-46ad-904d-828ccbb47352
名前 / ファイル | ライセンス | アクション |
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Halder-2019-Nanoassemblies of ultrasmall clust (2.4 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-07-04 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Halder, Avik
× Halder, Avik× Kioseoglou, Joseph× Yang, Bing× Kolipaka, Karthika Lakshmi× Seifert, Soenke× Ilavsky, Jan× Pellin, Michael× Sowwan, Mukhles× Grammatikopoulos, Panagiotis× Vajda, Stefan |
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書誌情報 |
en : Nanoscale 巻 11, 号 11, p. 4683-4687, 発行日 2019-02-20 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Cu nanoassemblies formed transiently during reaction from size-selected subnanometer Cu4 clusters supported on amorphous OH-terminated alumina convert CO2 into methanol and hydrocarbons under near-atmospheric pressure at rates considerably higher than those of individually standing Cu4 clusters. An in situ characterization reveals that the clusters self-assemble into 2D nanoassemblies at higher temperatures which then disintegrate upon cooling down to room temperature. DFT calculations postulate a formation mechanism of these nanoassemblies by hydrogen-bond bridges between the clusters and H2O molecules, which keep the building blocks together while preventing their coalescence. | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2040-3364 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2040-3372 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/30783643 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1039/C8NR06664G | |||||
権利 | ||||||
権利情報 | © 2019 The Royal Society of Chemistry. | |||||
情報源 | ||||||
関連名称 | https://creativecommons.org/licenses/by-nc/3.0/ | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2019/nr/c8nr06664g#!divAbstract | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |