Solvent-Tunable Exciton-Charge Transfer Mixed State Enhances Emission of Functionalized Benzo[rst]pentaphene through Symmetry Breaking

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Item Type	学術雑誌論文 / Journal Article
Language	English
Author	Xiushang Xu Amy L. Vonder Haar Rengo Yoshioka Qizheng Zhang Serhii Vasylevskyi Andrew J Musser Akimitsu Narita
Journal or Publication Title	Chemical Communications
Volume	59
Number	6
Page Range	720 - 723
Year	2022-12-12
Abstract	A benzo[rst]pentaphene (BPP) substituted by two bis(methoxyphenyl)amino (MeOPA) groups (BPP-MeOPA) was synthesized and clearly characterized by NMR and single-crystal X-ray analysis. Detailed investigations of its photophysical properties, including transient absorption spectroscopy analyses, revealed that the introduction of the MeOPA groups breaks the symmetry of the BPP core, improving its absorption and emission from an S1 state with both excitonic and charge-transfer character.
Publisher	Royal Society of Chemistry
ISSN	1359-7345 1364-548X
DOI	info:doi/10.1039/D2CC05369A
Rights	© 2022 The Author(s)
Related site	https://pubs.rsc.org/en/Content/ArticleLanding/2023/CC/D2CC05369A
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