{"created":"2023-06-26T11:00:41.392098+00:00","id":1226,"links":{},"metadata":{"_buckets":{"deposit":"8e307f11-7707-4e7e-8f13-d4d1d95256f6"},"_deposit":{"created_by":27,"id":"1226","owners":[27],"pid":{"revision_id":0,"type":"depid","value":"1226"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001226","sets":["6:35"]},"author_link":["6781","6783","6782","6784"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-03-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1594","bibliographicPageStart":"1581","bibliographicVolumeNumber":"38","bibliographic_titles":[{},{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Lapointe, Sébastien"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khaskin, Eugene"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"The electronic and steric properties of a new class of electron-rich and sterically hindered tertamethylated PNP pincer ligands (Me4PNPR = 2,6-bisRdialkylphosphino)propylipyridine with R = Pr-i, Bu-t) are discussed. Introducing the methyl groups on the pincer arm prevents dearomatization of the pincer framework and increases the bulkiness and electron-donating capacity of the ligand. Highly reactive Ni-I species are thus prevented from dimerizing and can be analyzed by a wide variety of spectroscopic methods. X-ray diffraction study shows that steric bulk has an important influence on the resulting geometric and spectroscopic properties of the Ni-I complexes. Complexes S and 6, which contain Pr-i groups on the phosphorus atoms, show a very rare seesaw geometry around the metal center, while Bu-t complexes 7 and 8 show a distorted square-planar geometry. Computational analysis reveals that the SOMO for all complexes has a d(x)(-y)(2)(2) character with the spin density mostly residing on the nickel.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acs.organomet.9b00026","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.organomet.9b00026","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2019 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.9b00026"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-6041","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-05"}],"displaytype":"detail","filename":"Ni_Manuscript_revised_20190218.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Ni_Manuscript_revised_20190218","url":"https://oist.repo.nii.ac.jp/record/1226/files/Ni_Manuscript_revised_20190218.pdf"},"version_id":"3954b62d-bee9-48ea-8b8a-844396ddcc80"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stable Nickel(I) Complexes with Electron-Rich, Sterically-Hindered, Innocent PNP Pincer Ligands","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stable Nickel(I) Complexes with Electron-Rich, Sterically-Hindered, Innocent PNP Pincer Ligands","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"27","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-03-05"},"publish_date":"2020-03-05","publish_status":"0","recid":"1226","relation_version_is_last":true,"title":["Stable Nickel(I) Complexes with Electron-Rich, Sterically-Hindered, Innocent PNP Pincer Ligands"],"weko_creator_id":"27","weko_shared_id":27},"updated":"2023-06-26T11:54:52.916923+00:00"}