{"created":"2023-06-26T11:00:44.858149+00:00","id":1311,"links":{},"metadata":{"_buckets":{"deposit":"595d8a5a-59f1-4605-a3af-7248225f094b"},"_deposit":{"created_by":29,"id":"1311","owners":[29],"pid":{"revision_id":0,"type":"depid","value":"1311"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001311","sets":["6:35"]},"author_link":["7643","7637","7642","7645","7640","7638","7644","7639","7641","7646"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-09-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"22","bibliographicPageEnd":"4419","bibliographicPageStart":"4409","bibliographicVolumeNumber":"38","bibliographic_titles":[{},{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sarbajna, Abir"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"He, Yu-Tao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Dinh, Minh Hoan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Gladkovskaya, Olga"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rahaman, S. M. Wahidur"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Karimata, Ayumu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khaskin, Eugene"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Lapointe, Sébastien"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"C–X bond reductive elimination and oxidative addition are key steps in many catalytic cycles for C–H functionalization catalyzed by precious metals; however, engaging first row transition metals in these overall 2e– processes remains a challenge. Although high-valent Mn aryl species have been implicated in Mn-catalyzed C–H functionalization, the nature and reactivity of such species remain unelucidated. In this work, we report rare examples of stable, cyclometalated monoaryl MnIII complexes obtained through clean oxidative addition of Ar–Br to MnI(CO)5Br. These isolated MnIII–Ar complexes undergo unprecedented 2e– reductive elimination of the Ar–X (X = Br, I, and CN) bond and MnII induced by 1e– oxidation, presumably via transient reactive MnIV species. Mechanistic studies suggest a nonradical pathway.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acs.organomet.9b00494","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.9b00494","subitem_relation_type_select":"DOI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2019 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Aryl–X Bond-Forming Reductive Elimination from High-Valent Mn–Aryl Complexes, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.9b00494."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-6041","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-11"}],"displaytype":"detail","filename":"Manuscript_N3CMn_revised_20190827.pdf","filesize":[{"value":"986.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript_N3CMn_revised_20190827","url":"https://oist.repo.nii.ac.jp/record/1311/files/Manuscript_N3CMn_revised_20190827.pdf"},"version_id":"59df8d00-b14e-4188-877c-e99d152788d9"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Aryl–X Bond-Forming Reductive Elimination from High-Valent Mn–Aryl Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Aryl–X Bond-Forming Reductive Elimination from High-Valent Mn–Aryl Complexes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"29","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-03-19"},"publish_date":"2020-03-19","publish_status":"0","recid":"1311","relation_version_is_last":true,"title":["Aryl–X Bond-Forming Reductive Elimination from High-Valent Mn–Aryl Complexes"],"weko_creator_id":"29","weko_shared_id":29},"updated":"2023-06-26T11:54:04.489989+00:00"}