{"created":"2023-06-26T11:00:53.127998+00:00","id":1478,"links":{},"metadata":{"_buckets":{"deposit":"32172085-5e27-4882-8a52-1e73f031c262"},"_deposit":{"created_by":28,"id":"1478","owners":[28],"pid":{"revision_id":0,"type":"depid","value":"1478"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001478","sets":["6:166","6:63"]},"author_link":["8943","8944","8942","8939","8940","8938","8941"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-02-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"1704","bibliographicPageStart":"1698","bibliographicVolumeNumber":"3","bibliographic_titles":[{},{"bibliographic_title":"ACS Applied Bio Materials","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Zhang, Shijin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Cortes, William"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sasaki, Toshio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Asahina, Shunsuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Natsuko, Asano"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang, Qizheng"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang, Ye"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Inspired by the mechanoresponsive orientation of actin filaments in cell, we introduce a design paradigm of synthetic molecular self-assembling fibrils that respond to external mechanical force by transforming from a macroscopically disorder state to a highly ordered uniaxial aligned state. The incorporation of aromatic-containing amino acids and negatively charged amino acids lead to self-assembly motifs that transform into uniform nanofibrils in acidic solution. Adjusting the pH level of aqueous solution introduces optimal negative charge to the surface of self-assembling nanofibrils inducing long-range electrostatic repulsion forming a nematic phase. Upon external mechanical force, nanofibrils align in the force direction. Via evaporation casting in capillary confinement, the solvated synthetic self-assembling nanofibrils transform into scalable lamellar domains. Adjusting capillary geometry and drying procedure offers further parameters for tuning the mesoscale alignment of nanofibrils generating a variety of interference colors. The design paradigm of mechanoresponsive alignment of self-assembled nanofibrils as an addition of nanofabrication techniques is potentially employable for realizing biomimetic optical structures.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acsabm.0c00011","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acsabm.0c00011","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2020 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Bio Materials, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acsabm.0c00011."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2576-6422","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-02-04"}],"displaytype":"detail","filename":"ACS applied bio materials SJZ.pdf","filesize":[{"value":"12.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACS applied bio materials SJZ","url":"https://oist.repo.nii.ac.jp/record/1478/files/ACS applied bio materials SJZ.pdf"},"version_id":"93cbdda4-9815-466e-aa0c-5bd9d2cf9889"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mechanoresponsive Alignment of Molecular Self-Assembled Negatively Charged Nanofibrils","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mechanoresponsive Alignment of Molecular Self-Assembled Negatively Charged Nanofibrils","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"28","path":["63","166"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-05-12"},"publish_date":"2020-05-12","publish_status":"0","recid":"1478","relation_version_is_last":true,"title":["Mechanoresponsive Alignment of Molecular Self-Assembled Negatively Charged Nanofibrils"],"weko_creator_id":"28","weko_shared_id":28},"updated":"2023-06-26T11:48:22.895034+00:00"}