{"created":"2023-06-26T11:00:55.944123+00:00","id":1530,"links":{},"metadata":{"_buckets":{"deposit":"e448b75a-64c4-4512-a280-f829d67f7c82"},"_deposit":{"created_by":28,"id":"1530","owners":[28],"pid":{"revision_id":0,"type":"depid","value":"1530"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001530","sets":["6:48"]},"author_link":["9268","9267","9266","9265","9263","9269","9264"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"14194","bibliographicPageStart":"14185","bibliographicVolumeNumber":"12","bibliographic_titles":[{},{"bibliographic_title":"ACS Applied Materials & Interfaces","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tong, Guoqing"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Jiang, Maowei"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Son, Dae-Yong"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Qiu, Longbin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Liu, Zonghao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ono, Luis K."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Qi, Yabing"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Control of forward and inverse reactions between perovskites and precursor materials is key to attaining high-quality perovskite materials. Many techniques focus on synthesizing nanostructured CsPbX3 materials (e.g., nanowires) via a forward reaction (CsX + PbX2 → CsPbX3). However, low solubility of inorganic perovskites and complex phase transition make it difficult to realize the precise control of composition and length of nanowires using the conventional forward approach. Herein, we report the self-assembly inverse growth of CsPbBr3 micronanowires (MWs) (CsPb2Br5 → CsPbBr3 + PbBr2↑) by controlling phase transition from CsPb2Br5 to CsPbBr3. The two-dimensional (2D) structure of CsPb2Br5 serves as nucleation sites to induce initial CsPbBr3 MW growth. Also, phase transition allows crystal rearrangement and slows down crystal growth, which facilitates the MW growth of CsPbBr3 crystals along the 2D planes of CsPb2Br5. A CsPbBr3 MW photodetector constructed based on the inverse growth shows a high responsivity of 6.44 A W–1 and detectivity of ∼1012 Jones. Large grain size, high crystallinity, and large thickness can effectively alleviate decomposition/degradation of perovskites, which leads to storage stability for over 60 days in humid environment (relative humidity = 45%) and operational stability for over 3000 min under illumination (wavelength = 400 nm, light intensity = 20.06 mW cm–2).","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_13":{"attribute_name":"PubMedNo.","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:pmid/32134239","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acsami.0c01056","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acsami.0c01056","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2020 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acsami.0c01056."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1944-8244","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1944-8252","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-03-05"}],"displaytype":"detail","filename":"MS.pdf","filesize":[{"value":"4.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"MS","url":"https://oist.repo.nii.ac.jp/record/1530/files/MS.pdf"},"version_id":"cd7ec768-1943-49bc-a4b5-6d3679fd17c9"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Inverse Growth of Large-Grain-Size and Stable Inorganic Perovskite Micronanowire Photodetectors","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Inverse Growth of Large-Grain-Size and Stable Inorganic Perovskite Micronanowire Photodetectors","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"28","path":["48"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-05-28"},"publish_date":"2020-05-28","publish_status":"0","recid":"1530","relation_version_is_last":true,"title":["Inverse Growth of Large-Grain-Size and Stable Inorganic Perovskite Micronanowire Photodetectors"],"weko_creator_id":"28","weko_shared_id":28},"updated":"2023-06-26T11:48:39.580108+00:00"}