{"created":"2023-06-26T11:00:59.086375+00:00","id":1593,"links":{},"metadata":{"_buckets":{"deposit":"d4d3056e-f4ea-481a-a293-17d9a93771e8"},"_deposit":{"created_by":29,"id":"1593","owners":[29],"pid":{"revision_id":0,"type":"depid","value":"1593"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001593","sets":["6:35"]},"author_link":["9566","9569","9567","9568"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-04-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"16","bibliographicPageEnd":"3852","bibliographicPageStart":"3844","bibliographicVolumeNumber":"11","bibliographic_titles":[{},{"bibliographic_title":"ChemCatChem","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Dubey, Abhishek"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rahaman, S. M. Wahidur"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Utilization of hydroxy‐substituted bipyridine ligands in transition metal catalysis mimicking [Fe]‐hydrogenase has been shown to be a promising approach in developing new catalysts for hydrogenation. For example, MnI complexes with 6,6′‐dihydroxy‐2,2′‐bipyridine ligand have been previously shown to be active catalysts for CO2 hydrogenation. In this work, simple bipyridine‐based Mn catalysts were developed that act as active catalysts for transfer hydrogenation of ketones, aldehydes and imines. For the first time, Mn‐catalyzed transfer hydrogenation of N ‐heterocycles was reported. The highest catalytic activity among complexes with variously substituted ligands was observed for the complex bearing two OH groups in bipyridine. Deuterium labeling experiments suggest a monohydride pathway.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"John Wiley & Sons"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1002/cctc.201900358","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/cctc.201900358","subitem_relation_type_select":"DOI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim"},{"subitem_rights":"This is the peer reviewed version of the following article: A. Dubey, S. M. W. Rahaman, R. R. Fayzullin, J. R. Khusnutdinova. Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes. ChemCatChem 2019, 11, 3844., which has been published in final form at https://doi.org/10.1002/cctc.201900358. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1867-3880","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1867-3899","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-04-02"}],"displaytype":"detail","filename":"Manuscript.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript","url":"https://oist.repo.nii.ac.jp/record/1593/files/Manuscript.pdf"},"version_id":"c610c993-2ca1-4bb2-9a73-d32b7d369ebf"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"29","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-07-02"},"publish_date":"2020-07-02","publish_status":"0","recid":"1593","relation_version_is_last":true,"title":["Transfer Hydrogenation of Carbonyl Groups, Imines and N‐Heterocycles Catalyzed by Simple, Bipyridine‐Based MnI Complexes"],"weko_creator_id":"29","weko_shared_id":29},"updated":"2023-06-26T11:47:05.581224+00:00"}