{"created":"2023-06-26T11:01:01.157111+00:00","id":1630,"links":{},"metadata":{"_buckets":{"deposit":"66d9deaa-14e5-4133-8b29-e0a4a116c4ab"},"_deposit":{"created_by":28,"id":"1630","owners":[28],"pid":{"revision_id":0,"type":"depid","value":"1630"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001630","sets":["6:167","6:35","6:81"]},"author_link":["9780","9778","9776","9779","9777"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"6815","bibliographicPageStart":"6810","bibliographicVolumeNumber":"10","bibliographic_titles":[{},{"bibliographic_title":"ACS Catalysis","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Vojkovsky, Tomas"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Deolka, Shubham"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Stepanova, Saiyyna"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Roy, Michael C."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khaskin, Eugene"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Sulfones and sulfonamides with an α-CH bond can be easily alkylated by aliphatic alcohols to add the carbon skeleton of the alcohol via a one-step, Ru(II)-catalyzed redox neutral reaction. The reaction requires a substoichiometric amount of base and produces only water as a byproduct. Several pharmaceutically relevant functional groups such as piperidine, morpholine, etc. are well-tolerated under the reaction conditions to give higher value-added products in one step from widely available substrates. The reaction proceeds through a sulfone carbanion addition to an in-situ-generated aldehyde formed via catalytic dehydrogenation and subsequent catalyst-mediated replacement of the secondary alcohol by hydrogen.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acscatal.0c00206","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/full/10.1021/acscatal.0c00206","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2020 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/full/10.1021/acscatal.0c00206."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2155-5435","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-20"}],"displaytype":"detail","filename":"Just Accepted online version-1.pdf","filesize":[{"value":"286.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Just Accepted online version-1","url":"https://oist.repo.nii.ac.jp/record/1630/files/Just Accepted online version-1.pdf"},"version_id":"0f7cf716-87bf-416e-91ef-b4ba02de11e4"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-11-26"}],"displaytype":"detail","filename":"SI Khaskin ACScatalysis _ modified after review 3-2.pdf","filesize":[{"value":"9.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SI Khaskin ACScatalysis _ modified after review 3-2","url":"https://oist.repo.nii.ac.jp/record/1630/files/SI Khaskin ACScatalysis _ modified after review 3-2.pdf"},"version_id":"2db49181-e3ed-4ee8-96af-00e8a070abd3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II)","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"28","path":["35","81","167"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-07-17"},"publish_date":"2020-07-17","publish_status":"0","recid":"1630","relation_version_is_last":true,"title":["Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II)"],"weko_creator_id":"28","weko_shared_id":28},"updated":"2023-06-26T11:42:40.849794+00:00"}