{"created":"2023-06-26T11:01:08.120734+00:00","id":1754,"links":{},"metadata":{"_buckets":{"deposit":"c6790695-16cf-42fc-9384-d0f383278c58"},"_deposit":{"created_by":28,"id":"1754","owners":[28],"pid":{"revision_id":0,"type":"depid","value":"1754"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001754","sets":["6:35"]},"author_link":["10538","10535","10539","10536","10537"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-08-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"36","bibliographicPageEnd":"12766","bibliographicPageStart":"12756","bibliographicVolumeNumber":"49","bibliographic_titles":[{},{"bibliographic_title":"Dalton Transactions","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Gallardo-Villagrán, Manuel"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rivada-Wheelaghan, Orestes"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rahaman, S. M. Wahidur"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"We report the synthesis and reactivity of RuII complexes with a new naphthyridinone-substituted phosphine ligand, 7-(diisopropylphosphinomethyl)-1,8-naphthyridin-2(1H)-one (L-H), which contains two reactive sites that can potentially be deprotonated by a strong base: an NH proton of naphthyridinone and a methylene arm attached to the phosphine. In the absence of a base, the stable bis-ligated complex Ru(L-H)2Cl2 (1) containing two NH groups in the secondary coordination sphere is formed. Upon further reaction with a base, a doubly deprotonated, dimeric complex is obtained, [Ru2(L*-H)2(L)2] (2), in which two of the four ligands undergo deprotonation at the NH (L), while the other two ligands are deprotonated at the methylene groups (L*-H) as confirmed by an X-ray diffraction study; intramolecular hydrogen bonding is present between the NH group of one ligand and an O-atom of another ligand in the dimeric structure, which stabilizes the observed geometry of the complex. Complex 2 reacts with protic solvents such as water or methanol generating aqua Ru(L)2(OH2)2 (3) or methanol complexes Ru(L)2(MeOH)2 (4), respectively, both exhibiting intramolecular H-bonded patterns with surrounding ligands at least in the solid state. These complexes react with benzyl alcohols to give aldehydes via base-free acceptorless dehydrogenation.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"The Royal Society of Chemistry"}]},"item_10001_relation_13":{"attribute_name":"PubMedNo.","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:pmid/32959855","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1039/D0DT02505D","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.rsc.org/en/content/articlelanding/2020/dt/d0dt02505d","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2020 The Author(s)."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1477-9226","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1477-9234","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-08-28"}],"displaytype":"detail","filename":"D0DT02505D-2.pdf","filesize":[{"value":"2.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"D0DT02505D-2","url":"https://oist.repo.nii.ac.jp/record/1754/files/D0DT02505D-2.pdf"},"version_id":"b937a63c-3fe6-4bf3-9167-bee5c938b3f4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Proton-responsive naphthyridinone-based RuII complexes and their reactivity with water and alcohols","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Proton-responsive naphthyridinone-based RuII complexes and their reactivity with water and alcohols","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"28","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-10-30"},"publish_date":"2020-10-30","publish_status":"0","recid":"1754","relation_version_is_last":true,"title":["Proton-responsive naphthyridinone-based RuII complexes and their reactivity with water and alcohols"],"weko_creator_id":"28","weko_shared_id":28},"updated":"2023-06-26T11:43:06.281644+00:00"}