{"created":"2023-06-26T11:01:12.811525+00:00","id":1865,"links":{},"metadata":{"_buckets":{"deposit":"8a386ade-51d2-452c-8d52-a76a3443863f"},"_deposit":{"created_by":27,"id":"1865","owners":[27],"pid":{"revision_id":0,"type":"depid","value":"1865"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00001865","sets":["6:35"]},"author_link":["11257","11262","11261","11258","11259","11260"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-10-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"23","bibliographicPageEnd":"5918","bibliographicPageStart":"5912","bibliographicVolumeNumber":"12","bibliographic_titles":[{},{"bibliographic_title":"ChemCatChem","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Rahaman, S. M. Wahidur"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Pandey, Dilip K."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rivada‐Wheelaghan, Orestes"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Dubey, Abhishek"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Hydrogenation of substituted styrenes and unactivated aliphatic alkenes by molecular hydrogen has been achieved using a Mn catalyst with a non‐pincer, picolylphosphine ligand. This is the second reported example of alkene hydrogenation catalyzed by a Mn complex. Mechanistic studies showed that a Mn hydride formed by H2 activation in the presence of a base is the catalytically active species. Based on experimental and DFT studies, H2 splitting is proposed to occur via a metal‐ligand cooperative pathway involving deprotonation of the CH2 arm of the ligand, leading to pyridine dearomatization.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH Verlag"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1002/cctc.202001158","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202001158","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: S. M. W. Rahaman, D. K. Pandey, O. Rivada-Wheelaghan, A. Dubey, R. R. Fayzullin, J. R. Khusnutdinova, ChemCatChem 2020, 12, 5912. , which has been published in final form at https://doi.org/10.1002/cctc.202001158. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1867-3880","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1867-3899","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-10-29"}],"displaytype":"detail","filename":"Rahaman-2020-Hydrogenation of alkenes catalyze.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Rahaman-2020-Hydrogenation of alkenes catalyze","url":"https://oist.repo.nii.ac.jp/record/1865/files/Rahaman-2020-Hydrogenation of alkenes catalyze.pdf"},"version_id":"0948239d-4f9a-410c-9754-5cdc1d2e8243"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Hydrogenation of Alkenes Catalyzed by a Non‐pincer Mn Complex","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Hydrogenation of Alkenes Catalyzed by a Non‐pincer Mn Complex","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"27","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-01-06"},"publish_date":"2021-01-06","publish_status":"0","recid":"1865","relation_version_is_last":true,"title":["Hydrogenation of Alkenes Catalyzed by a Non‐pincer Mn Complex"],"weko_creator_id":"27","weko_shared_id":27},"updated":"2023-06-26T11:40:03.021499+00:00"}