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Development of Red-Emissive Mechanoresponsive Polymers Incorporating Dynamic Photoluminescent Copper(I)-Pyridinophane-Arylamide Mechanophores
https://doi.org/10.15102/0002000962
https://doi.org/10.15102/000200096230180dee-50e0-43d0-90aa-d963f963c6a4
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GridnevaTatianaFulltext.pdf (15.2 MB)
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GridnevaTatianaExamAbstract.pdf (48 KB)
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| Item type | 学位論文 / Thesis or Dissertation(1) | |||||||
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| PubDate | 2025-08-14 | |||||||
| Title | ||||||||
| Title | 動的な発光性銅(I)-ピリジノファン-アリルアミドメカノフォアを組み込んだ赤色発光力学的刺激応答性ポリマーの開発 | |||||||
| Language | ja | |||||||
| Title | ||||||||
| Title | Development of Red-Emissive Mechanoresponsive Polymers Incorporating Dynamic Photoluminescent Copper(I)-Pyridinophane-Arylamide Mechanophores | |||||||
| Language | en | |||||||
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| Language | eng | |||||||
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| Subject Scheme | Other | |||||||
| Subject | mechanoresponsive polymers | coordination chemistry | |||||||
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| Resource Type Identifier | http://purl.org/coar/resource_type/c_db06 | |||||||
| Resource Type | doctoral thesis | |||||||
| Identifier Registration | ||||||||
| Identifier Registration | 10.15102/0002000962 | |||||||
| Identifier Registration Type | JaLC | |||||||
| Access Right | ||||||||
| Access Rights | open access | |||||||
| Access Rights URI | http://purl.org/coar/access_right/c_abf2 | |||||||
| Author |
Gridneva, Tatiana
× Gridneva, Tatiana
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| Abstract | ||||||||
| Description Type | Abstract | |||||||
| Description | This thesis describes the preparation, photophysical studies and computational studies of the photoluminescent copper(I)-pyridinophane-arylamide complexes, as well as the mechanoresponsive properties of poly(butyl acrylate) films incorporating these complexes as cross-linkers. First, an introduction will be given on the recent development of mechanoresponsive polymers covalently incorporating organic or organometallic mechanophores. The metal complex-based mechanophore systems will be then introduced, followed by the previous work in our group on the development of copper(I)-iodide and copper(I)-NHC photoluminescent mechanophores bearing a conformationally dynamic N4 pyridinophane macrocyclic ligand. In the following chapter, novel copper(I)-pyridinophane-arylamide complexes will be introduced. Their preparation, characterization, photophysical properties, electrochemical properties as well as the conformationally fluxional behavior in solution will be discussed, supported by computational studies. In the final chapter, synthesis and properties of mechanoresponsive polymers incorporating the copper(I)-pyridinophane-arylamide complexes as mechanophores will be presented. Optimization of the preparation method, photophysical properties and the mechanoresponsive properties of these polymers will be discussed. |
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| Language | en | |||||||
| Exam Date | ||||||||
| 2025-06-05 | ||||||||
| Degree Conferral Date | ||||||||
| Date Granted | 2025-07-31 | |||||||
| Degree | ||||||||
| Degree Name | Doctor of Philosophy | |||||||
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| Dissertation Number | 甲第197号 | |||||||
| Degree Conferrral Institution | ||||||||
| Degree Grantor Name Identifier Scheme | kakenhi | |||||||
| Degree Grantor Name Identifier | 38005 | |||||||
| Degree Grantor Name | Okinawa Institute of Science and Technology Graduate University | |||||||
| Version Format | ||||||||
| Version Type | VoR | |||||||
| Version Type Resource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| Copyright Information | ||||||||
| Rights | © 2025 The Author. | |||||||
