{"created":"2023-06-26T11:01:34.199892+00:00","id":2308,"links":{},"metadata":{"_buckets":{"deposit":"74d843a3-ddb3-49c5-afd1-50713033d049"},"_deposit":{"created_by":31,"id":"2308","owners":[31],"pid":{"revision_id":0,"type":"depid","value":"2308"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00002308","sets":["6:35"]},"author_link":["15318","15320","15319","15316","15321","15317","15315"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-04-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"2331","bibliographicPageStart":"2320","bibliographicVolumeNumber":"40","bibliographic_titles":[{},{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"He, Yu-Tao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Karimata, Ayumu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Gladkovskaya, Olga"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khaskin, Eugene"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sarbajna, Abir"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Manganese complexes have been considered as a cheap and readily available alternative to commonly used precious metal catalysts in C–C bond coupling reactions. Although high-valent Mn aryl intermediates have been proposed in such reactions, a mechanistic understanding of possible organometallic intermediates in Mn-mediated C–C coupling is still lacking due to their high reactivity. We report the synthesis of stable, isolable Mn(III) aryl complexes obtained by oxidative addition of aryl bromide or aryl chloride. These complexes react with a range of organometallic alkylating or arylating reagents (alkyl and aryl Grignard reagents, MeLi, ZnMe2) to undergo C(sp2)–C(sp3) or C(sp2)–C(sp2) bond coupling, and a preliminary catalytic system could be demonstrated. The reagent scope and yield of the C(sp2)–C(sp3) coupled product can further be increased by addition of TEMPO as an oxidant, generating alkyl radicals.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acs.organomet.1c00047","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.organomet.1c00047","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.organomet.1c00047"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-6041","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-04-16"}],"displaytype":"detail","filename":"Mn_CC_OM_repository.pdf","filesize":[{"value":"870.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Mn_CC_OM_repository","url":"https://oist.repo.nii.ac.jp/record/2308/files/Mn_CC_OM_repository.pdf"},"version_id":"c5b78e17-aa68-4c2a-8fa9-3d2e07508c41"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Reagents","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative addition","subitem_subject_scheme":"Other"},{"subitem_subject":"Addition reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"Chemical reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"Transition metals","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"C–C Bond Elimination from High-Valent Mn Aryl Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"C–C Bond Elimination from High-Valent Mn Aryl Complexes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"31","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-09-28"},"publish_date":"2021-09-28","publish_status":"0","recid":"2308","relation_version_is_last":true,"title":["C–C Bond Elimination from High-Valent Mn Aryl Complexes"],"weko_creator_id":"31","weko_shared_id":31},"updated":"2023-06-26T11:33:15.153856+00:00"}