{"created":"2023-06-26T11:01:42.083316+00:00","id":2455,"links":{},"metadata":{"_buckets":{"deposit":"ac32b5fe-9274-4f93-9cec-b85b3447f719"},"_deposit":{"created_by":31,"id":"2455","owners":[31],"pid":{"revision_id":0,"type":"depid","value":"2455"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00002455","sets":["6:35","6:81"]},"author_link":["16468","16467","16469"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-11-29","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{},{"bibliographic_title":"Chemistry – A European Journal","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Deolka, Shubham"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fayzullin, Robert R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khaskin, Eugene"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"We synthesized two 4Me−PNP ligands which block metal-ligand cooperation (MLC) with the Ru center and compared their Ru complex chemistry to their two traditional analogues used in acceptorless alcohol dehydrogenation catalysis. The corresponding 4Me−PNP complexes, which do not undergo dearomatization upon addition of base, allowed us to obtain rare, albeit unstable, 16 electron mono-CO Ru(0) complexes. Reactivity with CO and H2 allows for stabilization and extensive characterization of bis-CO Ru(0) 18 electron and Ru(II) cis and trans dihydride species that were also shown to be capable of C(sp2) −H activation. Reactivity and catalysis are contrasted to non-methylated Ru(II) species, showing that an MLC pathway is not necessary, with dramatic differences in outcomes during catalysis between iPr and tBu PNP complexes within each of the 4Me and non-methylated backbone PNP series being observed. Unusual intermediates are characterized in one of the new and one of the traditional complexes, and a common catalysis deactivation pathway was identified.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Wiley‐VCH GmbH"},{"subitem_publisher":"Chemistry Europe"}]},"item_10001_relation_13":{"attribute_name":"PubMedNo.","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:pmid/34741487","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1002/chem.202103778","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202103778","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Deolka, S., Fayzullin, R.R. and Khaskin, E. (2022), Bulky PNP Ligands Blocking Metal-Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation. Chem. Eur. J.., which has been published in final form at https://doi.org/10.1002/chem.202103778. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1521-3765","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-11-29"}],"displaytype":"detail","filename":"BulkyPNP_AM.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"BulkyPNP_AM","url":"https://oist.repo.nii.ac.jp/record/2455/files/BulkyPNP_AM.pdf"},"version_id":"d3199501-565a-4e58-b7f1-393d6ea0c8d8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"dehydrogenation","subitem_subject_scheme":"Other"},{"subitem_subject":"homogenous catalysis ligand design","subitem_subject_scheme":"Other"},{"subitem_subject":"metal-ligand cooperation","subitem_subject_scheme":"Other"},{"subitem_subject":"ruthenium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Bulky PNP Ligands Blocking Metal‐Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Bulky PNP Ligands Blocking Metal‐Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"31","path":["35","81"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-01-07"},"publish_date":"2022-01-07","publish_status":"0","recid":"2455","relation_version_is_last":true,"title":["Bulky PNP Ligands Blocking Metal‐Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation"],"weko_creator_id":"31","weko_shared_id":31},"updated":"2023-06-26T11:29:33.123565+00:00"}