@article{oai:oist.repo.nii.ac.jp:00002590,
 author = {Liu, Yuqiang and Ono, Luis K. and Tong, Guoqing and Bu, Tongle and Zhang, Hui and Ding, Chenfeng and Zhang, Wei and Qi, Yabing},
 issue = {47},
 journal = {Journal of the American Chemical Society},
 month = {Nov},
 note = {The spectral instability issue is a challenge in blue perovskite light-emitting diodes (PeLEDs). Dion–Jacobson (DJ) phase perovskites are promising alternatives to achieve high-quality blue PeLEDs. However, the current exploration of DJ phase perovskites is focused on symmetric divalent cations, and the corresponding efficiency of blue PeLEDs is still inferior to that of green and red ones. In this work, we report a new type of DJ phase CsPb(Br/Cl)3 perovskite via introduction of an asymmetric molecular configuration as the organic spacer cation in perovskites. The primary and tertiary ammonium groups on the asymmetric cations bridge with the lead halide octahedra forming the DJ phase structures. Stable photoluminescence spectra were demonstrated in perovskite films owing to the suppressed halide segregation. Meanwhile, the radiative recombination efficiency of charges is improved significantly as a result of the confinement effects and passivation of charge traps. Finally, we achieved an external quantum efficiency of 2.65% in blue PeLEDs with stable spectra emission under applied bias voltages. To our best knowledge, this is the first report of asymmetric cations used in PeLEDs, which provides a facile solution to the halide segregation issue in PeLEDs.},
 pages = {19711--19718},
 title = {Spectral Stable Blue-Light-Emitting Diodes via Asymmetric Organic Diamine Based Dion–Jacobson Perovskites},
 volume = {143},
 year = {2021}
}