{"created":"2023-06-26T11:01:56.100399+00:00","id":2691,"links":{},"metadata":{"_buckets":{"deposit":"aa74ae74-1e5c-4314-95f4-7f82a4a82bd2"},"_deposit":{"created_by":31,"id":"2691","owners":[31],"pid":{"revision_id":0,"type":"depid","value":"2691"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00002691","sets":["6:228"]},"author_link":["17407","17406","17405"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-04-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"6135","bibliographicPageStart":"6123","bibliographicVolumeNumber":"144","bibliographic_titles":[{},{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Mayhugh, Amy L."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yadav, Preeti"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Luscombe, Christine K."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Simple and efficient methods are a key consideration for small molecule and polymer syntheses. Direct arylation polymerization (DArP) is of increasing interest for preparing conjugated polymers as an effective approach compared to conventional cross-coupling polymerizations. As DArP sees broader utilization, advancements are needed to access materials with improved properties and different monomer structures and to improve the scalability of conjugated polymer synthesis. Presented herein are considerations for developing new methods of conjugated polymer synthesis from small molecule transformations, exploring how DArP has successfully used this approach, and presenting how emerging polymerization methodologies are developing similarly. While it is common to adapt small molecule methods to polymerizations, we demonstrate the ways in which information gained from studying polymerizations can inform and inspire greater advancements in small molecule transformations. This circular approach to organic synthetic method development underlines the value of collaboration between small molecule and polymer-based synthetic research groups.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_13":{"attribute_name":"PubMedNo.","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:pmid/35380440","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/jacs.1c12455","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/jacs.1c12455","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2022 The Author(s)."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-5126","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-07-06"}],"displaytype":"detail","filename":"Mayhugh-2022-Circular Discovery in Small Molec_Redacted.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","license_note":"CC BY-NC-ND 4.0\nCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International(https://creativecommons.org/licenses/by-nc-nd/4.0/)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Mayhugh-2022-Circular Discovery in Small Molec_Redacted","url":"https://oist.repo.nii.ac.jp/record/2691/files/Mayhugh-2022-Circular Discovery in Small Molec_Redacted.pdf"},"version_id":"b984e73a-d433-47da-aad7-0e422422d294"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"31","path":["228"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-07-06"},"publish_date":"2022-07-06","publish_status":"0","recid":"2691","relation_version_is_last":true,"title":["Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology"],"weko_creator_id":"31","weko_shared_id":31},"updated":"2023-06-26T11:26:27.279522+00:00"}