{"created":"2023-06-26T11:02:04.219051+00:00","id":2841,"links":{},"metadata":{"_buckets":{"deposit":"fe73927d-72e7-4a53-a619-c210cac14b32"},"_deposit":{"created_by":31,"id":"2841","owners":[31],"pid":{"revision_id":0,"type":"depid","value":"2841"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00002841","sets":["6:35"]},"author_link":["18160","18158","18159"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-10-28","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{},{"bibliographic_title":"Chemical Science","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Govindarajan, R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Deolka, Shubham"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khusnutdinova, Julia R."}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Heterobi- and multimetallic complexes providing close proximity between several metal centers serve as active species in artificial and enzymatic catalysis, and in model systems, showing unique modes of metal–metal cooperative bond activation. Through the rational design of well-defined, unsymmetrical ligand scaffolds, we create a convenient approach to support the assembly of heterometallic species in a well-defined and site-specific manner, preventing them from scrambling and dissociation. In this perspective, we will outline general strategies for the design of unsymmetrical ligands to support heterobi- and multimetallic complexes that show reactivity in various types of heterometallic cooperative bond activation.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1039/D2SC04263K","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.rsc.org/en/content/articlelanding/2022/SC/D2SC04263K","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2022 The Author(s)"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2041-6520","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"2041-6539","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-11-14"}],"displaytype":"detail","filename":"Govindarajan-2022-Heterometallic bond activati_VoR.pdf","filesize":[{"value":"4.7 MB"}],"format":"application/pdf","licensetype":"license_9","mimetype":"application/pdf","url":{"label":"Govindarajan-2022-Heterometallic bond activati_VoR","url":"https://oist.repo.nii.ac.jp/record/2841/files/Govindarajan-2022-Heterometallic bond activati_VoR.pdf"},"version_id":"147bc49a-506f-47b6-8e5a-9f5be354d58c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"31","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-11-14"},"publish_date":"2022-11-14","publish_status":"0","recid":"2841","relation_version_is_last":true,"title":["Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites"],"weko_creator_id":"31","weko_shared_id":31},"updated":"2023-06-26T11:22:54.189736+00:00"}