{"created":"2023-06-26T11:00:12.659775+00:00","id":452,"links":{},"metadata":{"_buckets":{"deposit":"a5f914bc-ecc6-4174-9991-659c6f61932d"},"_deposit":{"created_by":27,"id":"452","owners":[27],"pid":{"revision_id":0,"type":"depid","value":"452"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00000452","sets":["6:61"]},"author_link":["1873","1872"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-07-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"3806","bibliographicPageStart":"3803","bibliographicVolumeNumber":"19","bibliographic_titles":[{},{"bibliographic_title":"Organic Letters","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Zhang, Dongxin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Fujie"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"To provide insight into aldol reaction catalysis, the relative frequencies of carbanion formation at each α-position of ketones under catalysis by DBU, proline, β-proline, and related catalysts were determined through the deuteration of the ketones in the presence of these catalysts. For selected cases, the deuteration rate was compared with the aldol reaction rate and whether the generated enolate/enamine resulted in return to the ketone or product formation was estimated.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_13":{"attribute_name":"PubMedNo.","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:pmid/28671473","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/acs.orglett.7b01676","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.orglett.7b01676","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2017 American Chemical Society"},{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. "}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1523-7060","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-07-25"}],"displaytype":"detail","filename":"OL deuteration 170627_2.pdf","filesize":[{"value":"830.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"OL deuteration 170627_2","url":"https://oist.repo.nii.ac.jp/record/452/files/OL deuteration 170627_2.pdf"},"version_id":"725e4613-403f-49b6-8bd7-3ffb76a60c96"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Determination of Relative Frequency of Carbanion Formation at α-Positions of Ketones under Aldol Reaction Catalysis Conditions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Determination of Relative Frequency of Carbanion Formation at α-Positions of Ketones under Aldol Reaction Catalysis Conditions","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"27","path":["61"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-07-25"},"publish_date":"2018-07-25","publish_status":"0","recid":"452","relation_version_is_last":true,"title":["Determination of Relative Frequency of Carbanion Formation at α-Positions of Ketones under Aldol Reaction Catalysis Conditions"],"weko_creator_id":"27","weko_shared_id":27},"updated":"2023-06-26T12:06:44.886773+00:00"}