{"created":"2023-06-26T11:00:19.790777+00:00","id":779,"links":{},"metadata":{"_buckets":{"deposit":"757861e7-9691-4eea-9d0d-3759677276a7"},"_deposit":{"created_by":26,"id":"779","owners":[26],"pid":{"revision_id":0,"type":"depid","value":"779"},"status":"published"},"_oai":{"id":"oai:oist.repo.nii.ac.jp:00000779","sets":["6:48"]},"author_link":["4010","4011","4012","4013"],"item_10001_biblio_info_7":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-03-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"690","bibliographicPageStart":"678","bibliographicVolumeNumber":"132","bibliographic_titles":[{},{"bibliographic_title":"Carbon","bibliographic_titleLang":"en"}]}]},"item_10001_creator_3":{"attribute_name":"Author","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kim, Taehoon"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Leyden, Matthew R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ono, Luis K."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Qi, Yabing"}],"nameIdentifiers":[{}]}]},"item_10001_description_5":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"A multi-layer of stacked-graphene (8 layers of basal planes) grown by chemical vapour deposition (CVD) is introduced as an artificial solid electrolyte interphase (SEI) layer onto a transition metal oxide cathode for lithium-ion batteries. The basal planes are generally regarded as a strong physical barrier that prevents lithium-ion diffusion, although it is believed that a small number of lithium-ions can migrate through the defect sites of the stacked layers. Interestingly, the unique design of the stacked-graphene perpendicular to the basal planes not only effectively suppresses the formation of instable SEI layers, but also achieves a reasonable amount of battery charge capacities. To correctly understand the impact from the stacked design, we further studied the rate kinetics difference between slow cycles (0.125 C→0.250 C→0.400 C→0.125 C) and rapid cycles (C→2 C→3 C→C). We propose that the clap-net like design of the stacked-graphene could enable the effective conducting pathway for electron transport, while protecting the active material inside. The magnetic measurements reveal the efficient Li+ (de)intercalation into graphene-layers. The artificial SEI also renders the electrode/electrolyte interface more stable against dynamic rate changes. The present approach provides a particular advantage in developing high stability battery that can be utilized at various charge rates.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/j.carbon.2018.02.103","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"Related site","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S0008622318302392","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"Rights","attribute_value_mlt":[{"subitem_rights":"© 2018 Elsevier Ltd."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0008-6223","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"Author's flag","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"MS.pdf Stacked-graphene-1.pdf","filesize":[{"value":"8.1 MB"}],"format":"application/pdf","license_note":"Creative Commons Attribution-NonCommercial-NoDerivatives License\n(http://creativecommons.org/Licenses/by-nc-nd/4.0/)","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"MS Stacked-graphene-1","url":"https://oist.repo.nii.ac.jp/record/779/files/MS.pdf Stacked-graphene-1.pdf"},"version_id":"707c2899-230e-41d3-9062-af1024f7cd65"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stacked-graphene layers as engineered solid-electrolyte interphase (SEI) grown by chemical vapour deposition for lithium-ion batteries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stacked-graphene layers as engineered solid-electrolyte interphase (SEI) grown by chemical vapour deposition for lithium-ion batteries","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"26","path":["48"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-03-02"},"publish_date":"2020-03-02","publish_status":"0","recid":"779","relation_version_is_last":true,"title":["Stacked-graphene layers as engineered solid-electrolyte interphase (SEI) grown by chemical vapour deposition for lithium-ion batteries"],"weko_creator_id":"26","weko_shared_id":-1},"updated":"2023-06-26T12:00:34.070429+00:00"}