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Triboluminescence of a new family of CuI–NHC complexes in crystalline solid and in amorphous polymer films
https://oist.repo.nii.ac.jp/records/1745
https://oist.repo.nii.ac.jp/records/174505e283f5-d958-45c1-8da7-5440d930e66c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
d0sc04442c (1.1 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2020-10-29 | |||||
| タイトル | ||||||
| タイトル | Triboluminescence of a new family of CuI–NHC complexes in crystalline solid and in amorphous polymer films | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者（英） |
Karimata, Ayumu
× Karimata, Ayumu× Patil, Pradnya H.× Fayzullin, Robert R.× Khaskin, Eugene× Lapointe, Sébastien× Khusnutdinova, Julia R. |
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| 書誌情報 |
en : Chemical Science 巻 11, 号 39, p. 10814-10820, 発行日 2020-09-21 |
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| 抄録 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Triboluminescent compounds that generate emission of light in response to mechanical stimulus are promising targets in the development of “smart materials” and damage sensors. Among triboluminescent metal complexes, rare-earth europium and terbium complexes are most widely used, while there is no systematic data on more readily available and inexpensive Cu complexes. We report a new family of photoluminescent Cu–NHC complexes that show bright triboluminescence (TL) in the crystal state visible in ambient indoor light under air. Moreover, when these complexes are blended into amorphous polymer films even at small concentrations, TL is easily observed. Observation of TL in polymer films overcomes the limitation of using crystals and opens up possibilities for the development of mechanoresponsive coatings and materials based on inexpensive metals such as Cu. Our results may also have implications for the understanding of the TL effect's origin in polymer films. | |||||
| 出版者 | ||||||
| 出版者 | Royal Society of Chemistry | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 2041-6520 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 2041-6539 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | info:doi/10.1039/D0SC04442C | |||||
| 権利 | ||||||
| 権利情報 | © 2020 The Royal Society of Chemistry | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc04442c#!divAbstract | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
