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Synthesis of Nonplanar Graphene Nanoribbon with Fjord Edges
https://oist.repo.nii.ac.jp/records/2125
https://oist.repo.nii.ac.jp/records/2125442098b4-95ed-4d02-9cfe-4c48a191479a
名前 / ファイル | ライセンス | アクション |
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Creative Commons Attribution 4.0 International(https://creativecommons.org/licenses/by/4.0/)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-05-24 | |||||
タイトル | ||||||
タイトル | Synthesis of Nonplanar Graphene Nanoribbon with Fjord Edges | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Yao, Xuelin
× Yao, Xuelin× Zheng, Wenhao× Osella, Silvio× Qiu, Zijie× Fu, Shuai× Schollmeyer, Dieter× Müller, Beate× Beljonne, David× Bonn, Mischa× Wang, Hai I.× Müllen, Klaus× Narita, Akimitsu |
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書誌情報 |
en : Journal of the American Chemical Society 巻 143, 号 15, p. 5654-5658, 発行日 2021-04-07 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | As a new family of semiconductors, graphene nanoribbons (GNRs), nanometer-wide strips of graphene, have appeared as promising candidates for next-generation nanoelectronics. Out-of-plane deformation of π-frames in GNRs brings further opportunities for optical and electronic property tuning. Here we demonstrate a novel fjord-edged GNR (FGNR) with a nonplanar geometry obtained by regioselective cyclodehydrogenation. Triphenanthro-fused teropyrene 1 and pentaphenanthro-fused quateropyrene 2 were synthesized as model compounds, and single-crystal X-ray analysis revealed their helically twisted conformations arising from the [5]helicene substructures. The structures and photophysical properties of FGNR were investigated by mass spectrometry and UV–vis, FT-IR, terahertz, and Raman spectroscopic analyses combined with theoretical calculations. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0002-7863 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1520-5126 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/33825484 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/jacs.1c01882 | |||||
権利 | ||||||
権利情報 | © 2021 The Author(s). | |||||
権利 | ||||||
権利情報 | ACS AuthorChoice with CC-BY. | |||||
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識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/jacs.1c01882 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |