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Controlled and Reversible Stepwise Growth of Linear Copper(I) Chains Enabled by Dynamic Ligand Scaffolds
https://oist.repo.nii.ac.jp/records/820
https://oist.repo.nii.ac.jp/records/8205cca626b-1fd5-4d3c-a310-cf2c49707db1
名前 / ファイル | ライセンス | アクション |
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ACIE2017_tosend (1.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-03-11 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Controlled and Reversible Stepwise Growth of Linear Copper(I) Chains Enabled by Dynamic Ligand Scaffolds | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Rivada-Wheelaghan, Orestes
× Rivada-Wheelaghan, Orestes× Aristizábal, Sandra L.× López-Serrano, Joaquín× Fayzullin, Robert R.× Khusnutdinova, Julia R. |
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書誌情報 |
en : Angewandte Chemie International Edition 巻 56, 号 51, p. 16267-16271, 発行日 2017-11-04 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Reversible stepwise chain growth in linear CuI assemblies can be achieved by using the dynamic, unsymmetric naphthyridinone‐based ligand scaffolds L1 and L2. With the same ligand scaffolds, the length of the linear copper chain can be varied from two to three and four copper atoms, and the nuclearity of the complex is easily controlled by the stepwise addition of a CuI precursor to gradually increase the chain length, or by the reductive removal of Cu atoms to decrease the chain length. This represents a rare example of a stepwise controlled chain growth in extended metal atom chains (EMACs). All complexes are formed with excellent selectivity, and the mutual transformations of the complexes of different nuclearity were found to be fast and reversible. These unusual rearrangements of metal chains of different nuclearities were achieved by a stepwise “sliding” movement of the naphthyridinone bridging fragment along the metal chain. | |||||
出版者 | ||||||
出版者 | John Wiley & Sons, Inc. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1433-7851 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1521-3773 | |||||
PubMed番号 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/29105241 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/anie.201709167 | |||||
権利 | ||||||
権利情報 | © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: Controlled and Reversible Stepwise Growth of Linear Copper(I) Chains Enabled by Dynamic Ligand Scaffolds, which has been published in final form at https://doi.org/10.1002/anie.201709167. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201709167 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |