WEKO3
アイテム
{"_buckets": {"deposit": "fd03ff6e-55c0-4961-aed7-ced1a0abce8b"}, "_deposit": {"created_by": 28, "id": "1312", "owners": [28], "pid": {"revision_id": 0, "type": "depid", "value": "1312"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00001312", "sets": ["48"]}, "author_link": ["7647", "7652", "7654", "7651", "7649", "7655", "7648", "7650", "7653"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-04-19", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageStart": "1800504", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{}, {"bibliographic_title": "Advanced Energy Materials", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Liang, Jia"}], "nameIdentifiers": [{"nameIdentifier": "7647", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Liu, Zonghao"}], "nameIdentifiers": [{"nameIdentifier": "7648", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Qiu, Longbin"}], "nameIdentifiers": [{"nameIdentifier": "7649", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hawash, Zafer"}], "nameIdentifiers": [{"nameIdentifier": "7650", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Meng, Lingqiang"}], "nameIdentifiers": [{"nameIdentifier": "7651", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wu, Zhifang"}], "nameIdentifiers": [{"nameIdentifier": "7652", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Jiang, Yan"}], "nameIdentifiers": [{"nameIdentifier": "7653", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ono, Luis K."}], "nameIdentifiers": [{"nameIdentifier": "7654", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Qi, Yabing"}], "nameIdentifiers": [{"nameIdentifier": "7655", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "In this work all-inorganic perovskite CsPbIBr2 are doped with Mn to compensate their shortcomings in band structure for the application of perovskite solar cells (PSCs). The novel Mn-doped all-inorganic perovskites, CsPb1-xMnxI1+2xBr2-2x, are prepared in ambient atmosphere. As the concentration of Mn2+ ions increases, the bandgaps of CsPb1-xMnxI1+2xBr2-2x decrease from 1.89 to 1.75 eV. Additionally, when the concentration of Mn dopants is appropriate, this novel Mn-doped all-inorganic perovskite film shows better crystallinity and morphology than its undoped counterpart. These advantages alleviate the energy loss in hole transfer and facilitate the charge-transfer in perovskites, therefore, PSCs based on these novel CsPb1-xMnxI1+2xBr2-2x perovskite films display better photovoltaic performance than the undoped CsPbIBr2 perovskite films. The reference CsPbIBr2 cell reaches a power conversion efficiency (PCE) of 6.14%, comparable with the previous reports. The CsPb1-xMnxI1+2xBr2-2x cells reach the highest PCE of 7.36% (when x= 0.005), an increase of 19.9% in PCE. Furthermore, the encapsulated CsPb0.995Mn0.005I1.01Br1.99 cells exhibit good stability in ambient atmosphere. The storage stability measurements on the encapsulated PSCs reveal that PCE is dropped by only 8% of the initial value after \u003e300 h in ambient. Such improved efficiency and stability are achieved using low-cost carbon electrodes (without expensive hole transport materials and Au electrodes).", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1002/aenm.201800504", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://onlinelibrary.wiley.com/doi/full/10.1002/aenm.201800504", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2018 WILEY‐VCH Verlag GmbH \u0026 Co. KGaA, Weinheim."}, {"subitem_rights": "This is the peer reviewed version of the following article: Jia Liang Zonghao Liu Longbin Qiu Zafer Hawash Lingqiang Meng Zhifang Wu Yan Jiang Luis K. Ono Yabing Qi, Adv. Energy Mater.2018, 8, 1800504., which has been published in final form at https://doi.org/10.1002/aenm.201800504. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1614-6832", "subitem_source_identifier_type": "ISSN"}, {"subitem_source_identifier": "1614-6840", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-04-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "1.pdf", "filesize": [{"value": "2.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2800000.0, "url": {"label": "1", "url": "https://oist.repo.nii.ac.jp/record/1312/files/1.pdf"}, "version_id": "07987c88-c292-4b9e-b02c-b4a00b3e60a6"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Enhancing Optical, Electronic, Crystalline, and Morphological Properties of Cesium Lead Halide by Mn Substitution for High-Stability All-Inorganic Perovskite Solar Cells with Carbon Electrodes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Enhancing Optical, Electronic, Crystalline, and Morphological Properties of Cesium Lead Halide by Mn Substitution for High-Stability All-Inorganic Perovskite Solar Cells with Carbon Electrodes", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "28", "path": ["48"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/1312", "pubdate": {"attribute_name": "公開日", "attribute_value": "2020-03-23"}, "publish_date": "2020-03-23", "publish_status": "0", "recid": "1312", "relation": {}, "relation_version_is_last": true, "title": ["Enhancing Optical, Electronic, Crystalline, and Morphological Properties of Cesium Lead Halide by Mn Substitution for High-Stability All-Inorganic Perovskite Solar Cells with Carbon Electrodes"], "weko_shared_id": 28}
Enhancing Optical, Electronic, Crystalline, and Morphological Properties of Cesium Lead Halide by Mn Substitution for High-Stability All-Inorganic Perovskite Solar Cells with Carbon Electrodes
https://oist.repo.nii.ac.jp/records/1312
https://oist.repo.nii.ac.jp/records/13129af31f2b-db01-443d-bd55-26dc69d82f61
名前 / ファイル | ライセンス | アクション |
---|---|---|
1 (2.8 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2020-03-23 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Enhancing Optical, Electronic, Crystalline, and Morphological Properties of Cesium Lead Halide by Mn Substitution for High-Stability All-Inorganic Perovskite Solar Cells with Carbon Electrodes | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Liang, Jia
× Liang, Jia× Liu, Zonghao× Qiu, Longbin× Hawash, Zafer× Meng, Lingqiang× Wu, Zhifang× Jiang, Yan× Ono, Luis K.× Qi, Yabing |
|||||
書誌情報 |
en : Advanced Energy Materials 巻 8, 号 20, p. 1800504, 発行日 2018-04-19 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | In this work all-inorganic perovskite CsPbIBr2 are doped with Mn to compensate their shortcomings in band structure for the application of perovskite solar cells (PSCs). The novel Mn-doped all-inorganic perovskites, CsPb1-xMnxI1+2xBr2-2x, are prepared in ambient atmosphere. As the concentration of Mn2+ ions increases, the bandgaps of CsPb1-xMnxI1+2xBr2-2x decrease from 1.89 to 1.75 eV. Additionally, when the concentration of Mn dopants is appropriate, this novel Mn-doped all-inorganic perovskite film shows better crystallinity and morphology than its undoped counterpart. These advantages alleviate the energy loss in hole transfer and facilitate the charge-transfer in perovskites, therefore, PSCs based on these novel CsPb1-xMnxI1+2xBr2-2x perovskite films display better photovoltaic performance than the undoped CsPbIBr2 perovskite films. The reference CsPbIBr2 cell reaches a power conversion efficiency (PCE) of 6.14%, comparable with the previous reports. The CsPb1-xMnxI1+2xBr2-2x cells reach the highest PCE of 7.36% (when x= 0.005), an increase of 19.9% in PCE. Furthermore, the encapsulated CsPb0.995Mn0.005I1.01Br1.99 cells exhibit good stability in ambient atmosphere. The storage stability measurements on the encapsulated PSCs reveal that PCE is dropped by only 8% of the initial value after >300 h in ambient. Such improved efficiency and stability are achieved using low-cost carbon electrodes (without expensive hole transport materials and Au electrodes). | |||||
出版者 | ||||||
出版者 | Wiley | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1614-6832 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1614-6840 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/aenm.201800504 | |||||
権利 | ||||||
権利情報 | © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. | |||||
権利 | ||||||
権利情報 | This is the peer reviewed version of the following article: Jia Liang Zonghao Liu Longbin Qiu Zafer Hawash Lingqiang Meng Zhifang Wu Yan Jiang Luis K. Ono Yabing Qi, Adv. Energy Mater.2018, 8, 1800504., which has been published in final form at https://doi.org/10.1002/aenm.201800504. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://onlinelibrary.wiley.com/doi/full/10.1002/aenm.201800504 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |