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電子豊富な PNP ピンサー配位子を有する新規遷移金属錯体
https://doi.org/10.15102/1394.00001790
https://doi.org/10.15102/1394.00001790b58b4e1a-2ce2-4e66-9599-86276183fac8
名前 / ファイル | ライセンス | アクション |
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Full_Text (10.5 MB)
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Final_Exam_Abstract (42.9 kB)
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Item type | 学位論文 / Thesis or Dissertation(1) | |||||||
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公開日 | 2021-03-19 | |||||||
タイトル | ||||||||
言語 | ja | |||||||
タイトル | 電子豊富な PNP ピンサー配位子を有する新規遷移金属錯体 | |||||||
タイトル | ||||||||
言語 | en | |||||||
タイトル | Nickel Complexes of New Electron-Rich, Sterically-Hindered PNP Pincer Ligands | |||||||
言語 | ||||||||
言語 | eng | |||||||
資源タイプ | ||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_db06 | |||||||
資源タイプ | doctoral thesis | |||||||
ID登録 | ||||||||
ID登録 | 10.15102/1394.00001790 | |||||||
ID登録タイプ | JaLC | |||||||
アクセス権 | ||||||||
アクセス権 | open access | |||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||
著者 (英) |
Lapointe, Sébastien
× Lapointe, Sébastien
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抄録 | ||||||||
内容記述タイプ | Other | |||||||
内容記述 | This thesis describes the synthesis, characterization and reactivity studies of nickel complexes of a new family of electron-rich, bulky PNP pincer ligands (PNP = 2,6-{R2PC(CH3)2}2-pyridine). The first chapter introduces the literature review of pincer complexes with a focus on nickel complexes and their applications. The second chapter introduces a new family of pyridine-based PNP pincer ligands that are based on the classic PNP framework, explores how the modified ligand influences the behavior of nickel complexes, and describes examples of mostly metal-based reactivity. This chapter mainly focuses on how this new family of PNP ligands can remain unreactive under specific reductive conditions, which allows the stabilization of complexes having unusual oxidation state of the metal center. The third chapter explores how it is possible to induce new types of ligand-based reactivity on the PNP pincer framework by blocking classical modes of metal-ligand cooperation, and how changes in the electronics and steric properties of the complex can lead to switching from metal-based reactivity to ligand-based reactivity. | |||||||
言語 | en | |||||||
口頭試問日 | ||||||||
2020-07-28 | ||||||||
学位授与年月日 | ||||||||
学位授与年月日 | 2020-08-31 | |||||||
学位名 | ||||||||
学位名 | Doctor of Philosophy | |||||||
学位授与番号 | ||||||||
学位授与番号 | 甲第59号 | |||||||
学位授与機関 | ||||||||
学位授与機関識別子Scheme | kakenhi | |||||||
学位授与機関識別子 | 38005 | |||||||
学位授与機関名 | Okinawa Institute of Science and Technology Graduate University | |||||||
著者版フラグ | ||||||||
出版タイプ | VoR | |||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
権利 | ||||||||
権利情報 | © 2020 The Author. |