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Conjugated Metal–Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity
https://oist.repo.nii.ac.jp/records/2610
https://oist.repo.nii.ac.jp/records/26106501b3f0-33f4-4ec1-937f-75e622b11bcb
名前 / ファイル | ライセンス | アクション |
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Macrocycle Paper - After Review 2_am (2.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2022-03-30 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Conjugated Metal–Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Zasada, Leo B.
× Zasada, Leo B.× Guio, Lorenzo× Kamin, Austin A.× Dhakal, Diwash× Monahan, Madison× Seidler, Gerald T.× Luscombe, Christine K.× Xiao, Dianne J. |
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書誌情報 |
en : Journal of the American Chemical Society 巻 144, 号 10, p. 4515-4521, 発行日 2022-03-07 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The dimensional reduction of solids into smaller fragments provides a route to achieve new physical properties and gain deeper insight into the extended parent structures. Here, we report the synthesis of CuTOTP-OR (TOTPn– = 2,3,6,7-tetraoxidotriphenylene), a family of copper-based macrocycles that resemble truncated fragments of the conductive two-dimensional (2D) metal–organic framework Cu3(HHTP)2 (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene). The planar metal–organic macrocycles self-assemble into ordered nanotubes with internal diameters of ∼2 nm and short interlayer distances of ∼3.20 Å. Strong π–π stacking interactions between macrocycles facilitate out-of-plane charge transport, and pressed pellet conductivities as high as 2(1) × 10–3 S cm–1 are observed. Peripheral alkyl functionalization enhances solution processability and enables the fabrication of thin-film field-effect transistor devices. Ambipolar charge transport is observed, suggesting that similar behavior may be operative in Cu3(HHTP)2. By coupling the attractive features of metal–organic frameworks with greater processability, these macrocycles enable facile device integration and a more nuanced understanding of out-of-plane charge transport in 2D conductive metal–organic frameworks. | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0002-7863 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1520-5126 | |||||
PubMed番号 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/35255217 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/jacs.1c12596 | |||||
権利 | ||||||
権利情報 | © 2022 American Chemical Society | |||||
権利 | ||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.1c12596. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/jacs.1c12596 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |