WEKO3
アイテム
{"_buckets": {"deposit": "666b943e-7232-43e2-adca-495a7fbb84ec"}, "_deposit": {"created_by": 31, "id": "2778", "owners": [31], "pid": {"revision_id": 0, "type": "depid", "value": "2778"}, "status": "published"}, "_oai": {"id": "oai:oist.repo.nii.ac.jp:00002778", "sets": ["35"]}, "author_link": ["17886", "17892", "17885", "17889", "17891", "17887", "17890", "17888"], "item_10001_biblio_info_7": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-08-09", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "35", "bibliographicPageEnd": "13434", "bibliographicPageStart": "13426", "bibliographicVolumeNumber": "51", "bibliographic_titles": [{}, {"bibliographic_title": "Dalton Transactions", "bibliographic_titleLang": "en"}]}]}, "item_10001_creator_3": {"attribute_name": "Author", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Karimata, Ayumu"}], "nameIdentifiers": [{"nameIdentifier": "17885", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Gridneva, Tatiana"}], "nameIdentifiers": [{"nameIdentifier": "17886", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Patil, Pradnya H."}], "nameIdentifiers": [{"nameIdentifier": "17887", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fayzullin, Robert R."}], "nameIdentifiers": [{"nameIdentifier": "17888", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Khaskin, Eugene"}], "nameIdentifiers": [{"nameIdentifier": "17889", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lapointe, Sébastien"}], "nameIdentifiers": [{"nameIdentifier": "17890", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Garcia-Roca, Alèria"}], "nameIdentifiers": [{"nameIdentifier": "17891", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Khusnutdinova, Julia R."}], "nameIdentifiers": [{"nameIdentifier": "17892", "nameIdentifierScheme": "WEKO"}]}]}, "item_10001_description_5": {"attribute_name": "Abstract", "attribute_value_mlt": [{"subitem_description": "Herein we report a series of CuI complexes supported by tetradentate RN4 pyridinophane ligands that coordinate to ethylene forming either mononuclear complexes with ethylene coordinated in an η2-mode or a binuclear complex where ethylene binds to two Cu atoms in a μ-η2-η2-mode, depending on the steric effects of the RN4 ligand and the reaction conditions. In the binuclear complex with bridging ethylene, the C[double bond, length as m-dash]C bond is significantly elongated, with a bond length of 1.444(8) Å according to X-ray diffraction analysis. This complex represents the only examination a μ-η2-η2-coordinated Cu–olefin complex reported to date, featuring one of the longest reported C[double bond, length as m-dash]C bonds. The spectroscopic characterization, structure, electrochemical properties and solution behavior are analyzed in this study. Coordination of ethylene was found to be reversible in these complexes and more favored in less sterically hindered RN4 ligands, so that ethylene binding is observed in a coordinating solvent (MeCN) environment. In the case of the MeN4 ligand, the ethylene complex is photoluminescent in the solid state. The ethylene binding modes in mono- and binuclear complexes are elucidated through Natural Bond Orbital and QTAIM analyses.", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_10001_relation_13": {"attribute_name": "PubMedNo.", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:pmid/35993504", "subitem_relation_type_select": "PMID"}}]}, "item_10001_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1039/D2DT02180C", "subitem_relation_type_select": "DOI"}}]}, "item_10001_relation_17": {"attribute_name": "Related site", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://pubs.rsc.org/en/content/articlelanding/2022/DT/D2DT02180C", "subitem_relation_type_select": "URI"}}]}, "item_10001_rights_15": {"attribute_name": "Rights", "attribute_value_mlt": [{"subitem_rights": "© 2022 The Royal Society of Chemistry"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1477-9226", "subitem_source_identifier_type": "ISSN"}, {"subitem_source_identifier": "1477-9234", "subitem_source_identifier_type": "ISSN"}]}, "item_10001_version_type_20": {"attribute_name": "Author\u0027s flag", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-08-09"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "D2DT02180C (1)_R2.pdf", "filesize": [{"value": "2.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2100000.0, "url": {"label": "D2DT02180C", "url": "https://oist.repo.nii.ac.jp/record/2778/files/D2DT02180C (1)_R2.pdf"}, "version_id": "915ac98c-8c23-49b6-9171-c0f8de0de6ea"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "31", "path": ["35"], "permalink_uri": "https://oist.repo.nii.ac.jp/records/2778", "pubdate": {"attribute_name": "公開日", "attribute_value": "2022-09-06"}, "publish_date": "2022-09-06", "publish_status": "0", "recid": "2778", "relation": {}, "relation_version_is_last": true, "title": ["Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands"], "weko_shared_id": 31}
Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands
https://oist.repo.nii.ac.jp/records/2778
https://oist.repo.nii.ac.jp/records/2778cdf09924-cec3-4ce5-9822-aedc07d457a1
名前 / ファイル | ライセンス | アクション |
---|---|---|
D2DT02180C (2.1 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2022-09-06 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Karimata, Ayumu
× Karimata, Ayumu× Gridneva, Tatiana× Patil, Pradnya H.× Fayzullin, Robert R.× Khaskin, Eugene× Lapointe, Sébastien× Garcia-Roca, Alèria× Khusnutdinova, Julia R. |
|||||
書誌情報 |
en : Dalton Transactions 巻 51, 号 35, p. 13426-13434, 発行日 2022-08-09 |
|||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Herein we report a series of CuI complexes supported by tetradentate RN4 pyridinophane ligands that coordinate to ethylene forming either mononuclear complexes with ethylene coordinated in an η2-mode or a binuclear complex where ethylene binds to two Cu atoms in a μ-η2-η2-mode, depending on the steric effects of the RN4 ligand and the reaction conditions. In the binuclear complex with bridging ethylene, the C[double bond, length as m-dash]C bond is significantly elongated, with a bond length of 1.444(8) Å according to X-ray diffraction analysis. This complex represents the only examination a μ-η2-η2-coordinated Cu–olefin complex reported to date, featuring one of the longest reported C[double bond, length as m-dash]C bonds. The spectroscopic characterization, structure, electrochemical properties and solution behavior are analyzed in this study. Coordination of ethylene was found to be reversible in these complexes and more favored in less sterically hindered RN4 ligands, so that ethylene binding is observed in a coordinating solvent (MeCN) environment. In the case of the MeN4 ligand, the ethylene complex is photoluminescent in the solid state. The ethylene binding modes in mono- and binuclear complexes are elucidated through Natural Bond Orbital and QTAIM analyses. | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1477-9226 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1477-9234 | |||||
PubMed番号 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | PMID | |||||
関連識別子 | info:pmid/35993504 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1039/D2DT02180C | |||||
権利 | ||||||
権利情報 | © 2022 The Royal Society of Chemistry | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2022/DT/D2DT02180C | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |