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Early stages of polycrystalline diamond deposition: laser reflectance at substrates with growing nanodiamonds
https://oist.repo.nii.ac.jp/records/2893
https://oist.repo.nii.ac.jp/records/2893f957e415-9cda-44bb-9afc-54761227d121
名前 / ファイル | ライセンス | アクション |
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d2na00723a (3.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2023-01-24 | |||||
タイトル | ||||||
タイトル | Early stages of polycrystalline diamond deposition: laser reflectance at substrates with growing nanodiamonds | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者(英) |
Vázquez-Cortés, David
× Vázquez-Cortés, David× Janssens, Stoffel D.× Sutisna, Burhannudin× Fried, Eliot |
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書誌情報 |
en : Nanoscale Advances 巻 5, 号 2, p. 412-424, 発行日 2022-12-01 |
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抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The chemical vapor deposition of polycrystalline diamond (PCD) films is typically done on substrates seeded with diamond nanoparticles. Specular laser reflectance has been used in tandem with a continuous film model to monitor the thickness of these films during their deposition. However, approaches to gain information on properties that strongly affect film morphology, such as the areal density of seeds, remain largely unexplored. This work outlines a strategy for using laser reflectance measurements to refine the monitoring of film thickness during deposition, estimate the mean equivalent radii and the areal density of seeds, and estimate growth incubation periods. We present a general model based on the Rayleigh theory of scattering for laser reflectance at substrates with growing nanoparticles that captures the early stages of PCD deposition. We test our model experimentally by depositing diamond under identical conditions on silicon substrates with various seed densities and by comparing seed densities obtained by scanning electron microscopy to those determined by our strategy. We also explore the different deposition stages for which our model and a continuous film model can be used safely. In addition to providing guidelines for characterizing PCD deposition, this work may also advance the general understanding of nanoparticle growth and formation. | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2516-0230 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1039/D2NA00723A | |||||
権利 | ||||||
権利情報 | © 2023 The Authors. | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2023/NA/D2NA00723A | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |