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Hydrogenation of Alkenes Catalyzed by a Non‐pincer Mn Complex
https://oist.repo.nii.ac.jp/records/1865
https://oist.repo.nii.ac.jp/records/186576816700-d0b2-4939-bde3-7ab21f1c5a4e
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Rahaman-2020-Hydrogenation of alkenes catalyze (1.4 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||
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| 公開日 | 2021-01-06 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Hydrogenation of Alkenes Catalyzed by a Non‐pincer Mn Complex | |||||||||||||||||
| 言語 | en | |||||||||||||||||
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| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 著者（英） |
Rahaman, S. M. Wahidur
× Rahaman, S. M. Wahidur
× Pandey, Dilip K.
× Rivada‐Wheelaghan, Orestes
× Dubey, Abhishek
× Fayzullin, Robert R.
× Khusnutdinova, Julia R.
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| 書誌情報 |
en : ChemCatChem 巻 12, 号 23, p. 5912-5918, 発行日 2020-10-28 |
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| 抄録 | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | Hydrogenation of substituted styrenes and unactivated aliphatic alkenes by molecular hydrogen has been achieved using a Mn catalyst with a non‐pincer, picolylphosphine ligand. This is the second reported example of alkene hydrogenation catalyzed by a Mn complex. Mechanistic studies showed that a Mn hydride formed by H2 activation in the presence of a base is the catalytically active species. Based on experimental and DFT studies, H2 splitting is proposed to occur via a metal‐ligand cooperative pathway involving deprotonation of the CH2 arm of the ligand, leading to pyridine dearomatization. | |||||||||||||||||
| 出版者 | ||||||||||||||||||
| 出版者 | Wiley-VCH Verlag | |||||||||||||||||
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| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 1867-3880 | |||||||||||||||||
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| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 1867-3899 | |||||||||||||||||
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| 関連タイプ | isVersionOf | |||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | info:doi/10.1002/cctc.202001158 | |||||||||||||||||
| 権利 | ||||||||||||||||||
| 権利情報 | This is the peer reviewed version of the following article: S. M. W. Rahaman, D. K. Pandey, O. Rivada-Wheelaghan, A. Dubey, R. R. Fayzullin, J. R. Khusnutdinova, ChemCatChem 2020, 12, 5912. , which has been published in final form at https://doi.org/10.1002/cctc.202001158. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||||||||||||||
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| 識別子タイプ | URI | |||||||||||||||||
| 関連識別子 | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202001158 | |||||||||||||||||
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| 出版タイプ | AM | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||||||
