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Lead halide–templated crystallization of methylamine-free perovskite for efficient photovoltaic modules

https://oist.repo.nii.ac.jp/records/2202
https://oist.repo.nii.ac.jp/records/2202
e7ea677d-567c-4db8-b24f-9cefa1ed2b6e
Name / File License Actions
Accepted Accepted Manuscript-TL-20210506 (1.7 MB)
Item type 学術雑誌論文 / Journal Article(1)
PubDate 2021-08-24
Title
Title Lead halide–templated crystallization of methylamine-free perovskite for efficient photovoltaic modules
Language en
Language
Language eng
Resource Type
Resource Type Identifier http://purl.org/coar/resource_type/c_6501
Resource Type journal article
Author Bu, Tongle

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Bu, Tongle

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Li, Jing

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Li, Jing

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Li, Hengyi

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Li, Hengyi

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Tian, Congcong

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Tian, Congcong

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Su, Jie

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Su, Jie

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Tong, Guoqing

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Tong, Guoqing

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Ono, Luis K.

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Ono, Luis K.

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Wang, Chao

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Wang, Chao

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Lin, Zhipeng

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Lin, Zhipeng

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Chai, Nianyao

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Chai, Nianyao

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Zhang, Xiao-Li

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Zhang, Xiao-Li

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Chang, Jingjing

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Chang, Jingjing

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Lu, Jianfeng

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Lu, Jianfeng

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Zhong, Jie

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Zhong, Jie

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Huang, Wenchao

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Huang, Wenchao

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Qi, Yabing

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Qi, Yabing

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Cheng, Yi-Bing

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Cheng, Yi-Bing

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Huang, Fuzhi

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Huang, Fuzhi

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Bibliographic Information en : Science

Volume Number 372, Issue Number 6548, p. 1327-1332, Issue Date 2021-06-18
Abstract
Description Type Other
Description Upscaling efficient and stable perovskite layers is one of the most challenging issues in the commercialization of perovskite solar cells. Here, a lead halide–templated crystallization strategy is developed for printing formamidinium (FA)–cesium (Cs) lead triiodide perovskite films. High-quality large-area films are achieved through controlled nucleation and growth of a lead halide•N-methyl-2-pyrrolidone adduct that can react in situ with embedded FAI/CsI to directly form α-phase perovskite, sidestepping the phase transformation from δ-phase. A nonencapsulated device with 23% efficiency and excellent long-term thermal stability (at 85°C) in ambient air (~80% efficiency retention after 500 hours) is achieved with further addition of potassium hexafluorophosphate. The slot die–printed minimodules achieve champion efficiencies of 20.42% (certified efficiency 19.3%) and 19.54% with an active area of 17.1 and 65.0 square centimeters, respectively.
Publisher
Publisher American Association for the Advancement of Science
ISSN
Source Identifier Type ISSN
Source Identifier 0036-8075
ISSN
Source Identifier Type ISSN
Source Identifier 1095-9203
PubMedNo.
Relation Type isVersionOf
Identifier Type PMID
Related Identifier info:pmid/34140385
DOI
Relation Type isVersionOf
Identifier Type DOI
Related Identifier info:doi/10.1126/science.abh1035
Rights
Rights © 2021 The Author(s).
Rights
Rights This is the author’s version of the work. It is posted here by permission of the AAAS for personal use, not for redistribution. The definitive version was published in Science on Vol. 372 and 18 Jun 2021, DOI: 10.1126/science.abh1035.
Related site
Identifier Type URI
Related Identifier https://science.sciencemag.org/content/372/6548/1327
Author's flag
Version Type AM
Version Type Resource http://purl.org/coar/version/c_ab4af688f83e57aa
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